Loading…
Novel Methods of Producing Low-Reflectance Coatings Utilizing Synergistic Effects of Polymer Phase Separation
Novel methods were developed to generate and characterize surface structures formed from polymer segregation within a powder coating system. A blend of unique acrylic polyol resins and low concentrations of matting agent afforded a durable coating exhibiting consistent low reflectance. An enhanced s...
Saved in:
Published in: | ACS applied materials & interfaces 2016-10, Vol.8 (39), p.26251-26257 |
---|---|
Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-a330t-15cb3b0533dfea95724251c6a740dfa466096edd586b8f8396b30d237712c4203 |
---|---|
cites | cdi_FETCH-LOGICAL-a330t-15cb3b0533dfea95724251c6a740dfa466096edd586b8f8396b30d237712c4203 |
container_end_page | 26257 |
container_issue | 39 |
container_start_page | 26251 |
container_title | ACS applied materials & interfaces |
container_volume | 8 |
creator | Giles, Spencer L Heller, Nicholas W. M Clayton, Clive R Walker, Mark E Wytiaz, Mark J Wynne, James H |
description | Novel methods were developed to generate and characterize surface structures formed from polymer segregation within a powder coating system. A blend of unique acrylic polyol resins and low concentrations of matting agent afforded a durable coating exhibiting consistent low reflectance. An enhanced synergistic effect was observed from the phase separation and domain formation of the two polymeric resins with varying pendent hydroxyl group functionality and the incorporated matting agents. Together the domains and incorporated matting agents produced a significantly lower reflectance coating than the matting agent in combination with either polymeric resin alone. The rigorous thermal, optical, and spectroscopic analysis of the pigmented coating and control coatings culminated in the complete characterization of polymeric phases within the resulting coatings. Raman analysis of the control coatings via a distinct spectroscopic handle allowed for positive identification of the segregated polymer resins within the coating structure. Domains observed by optical microscopy within the control coating structure were chemically identified via Raman analysis as the high-hydroxyl content resin. Subsequent Raman mapping of the peak intensity over an entire cross-section provided consistent evidence for positive identification of the polymeric composition within the domain. |
doi_str_mv | 10.1021/acsami.6b06037 |
format | article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1835350736</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1835350736</sourcerecordid><originalsourceid>FETCH-LOGICAL-a330t-15cb3b0533dfea95724251c6a740dfa466096edd586b8f8396b30d237712c4203</originalsourceid><addsrcrecordid>eNp1kEtLw0AURgdRbH1sXcosRUidd5KllPqAqsXHOkwmd2xKkqkziVJ_vSmp7lzdy-V8H9yD0BklE0oYvdIm6LqcqJwowuM9NKapEFHCJNv_24UYoaMQVoQozog8RCMWK6aUEGNUP7pPqPADtEtXBOwsXnhXdKZs3vHcfUXPYCswrW4M4KnTbX8P-K0tq_J7i7xsGvDvZWhLg2fW9uTQ4apNDR4vljoAfoG19n3UNSfowOoqwOluHqO3m9nr9C6aP93eT6_nkeactBGVJuc5kZwXFnQqYyaYpEbpWJDCaqEUSRUUhUxUntiEpyrnpGA8jikzghF-jC6G3rV3Hx2ENqvLYKCqdAOuCxlNuOSSxFz16GRAjXcheLDZ2pe19puMkmyrOBsUZzvFfeB8193lNRR_-K_THrgcgD6YrVznm_7V_9p-ADx3hqY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1835350736</pqid></control><display><type>article</type><title>Novel Methods of Producing Low-Reflectance Coatings Utilizing Synergistic Effects of Polymer Phase Separation</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)</source><creator>Giles, Spencer L ; Heller, Nicholas W. M ; Clayton, Clive R ; Walker, Mark E ; Wytiaz, Mark J ; Wynne, James H</creator><creatorcontrib>Giles, Spencer L ; Heller, Nicholas W. M ; Clayton, Clive R ; Walker, Mark E ; Wytiaz, Mark J ; Wynne, James H</creatorcontrib><description>Novel methods were developed to generate and characterize surface structures formed from polymer segregation within a powder coating system. A blend of unique acrylic polyol resins and low concentrations of matting agent afforded a durable coating exhibiting consistent low reflectance. An enhanced synergistic effect was observed from the phase separation and domain formation of the two polymeric resins with varying pendent hydroxyl group functionality and the incorporated matting agents. Together the domains and incorporated matting agents produced a significantly lower reflectance coating than the matting agent in combination with either polymeric resin alone. The rigorous thermal, optical, and spectroscopic analysis of the pigmented coating and control coatings culminated in the complete characterization of polymeric phases within the resulting coatings. Raman analysis of the control coatings via a distinct spectroscopic handle allowed for positive identification of the segregated polymer resins within the coating structure. Domains observed by optical microscopy within the control coating structure were chemically identified via Raman analysis as the high-hydroxyl content resin. Subsequent Raman mapping of the peak intensity over an entire cross-section provided consistent evidence for positive identification of the polymeric composition within the domain.</description><identifier>ISSN: 1944-8244</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.6b06037</identifier><identifier>PMID: 27626644</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>ACS applied materials & interfaces, 2016-10, Vol.8 (39), p.26251-26257</ispartof><rights>Copyright © 2016 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a330t-15cb3b0533dfea95724251c6a740dfa466096edd586b8f8396b30d237712c4203</citedby><cites>FETCH-LOGICAL-a330t-15cb3b0533dfea95724251c6a740dfa466096edd586b8f8396b30d237712c4203</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27626644$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Giles, Spencer L</creatorcontrib><creatorcontrib>Heller, Nicholas W. M</creatorcontrib><creatorcontrib>Clayton, Clive R</creatorcontrib><creatorcontrib>Walker, Mark E</creatorcontrib><creatorcontrib>Wytiaz, Mark J</creatorcontrib><creatorcontrib>Wynne, James H</creatorcontrib><title>Novel Methods of Producing Low-Reflectance Coatings Utilizing Synergistic Effects of Polymer Phase Separation</title><title>ACS applied materials & interfaces</title><addtitle>ACS Appl. Mater. Interfaces</addtitle><description>Novel methods were developed to generate and characterize surface structures formed from polymer segregation within a powder coating system. A blend of unique acrylic polyol resins and low concentrations of matting agent afforded a durable coating exhibiting consistent low reflectance. An enhanced synergistic effect was observed from the phase separation and domain formation of the two polymeric resins with varying pendent hydroxyl group functionality and the incorporated matting agents. Together the domains and incorporated matting agents produced a significantly lower reflectance coating than the matting agent in combination with either polymeric resin alone. The rigorous thermal, optical, and spectroscopic analysis of the pigmented coating and control coatings culminated in the complete characterization of polymeric phases within the resulting coatings. Raman analysis of the control coatings via a distinct spectroscopic handle allowed for positive identification of the segregated polymer resins within the coating structure. Domains observed by optical microscopy within the control coating structure were chemically identified via Raman analysis as the high-hydroxyl content resin. Subsequent Raman mapping of the peak intensity over an entire cross-section provided consistent evidence for positive identification of the polymeric composition within the domain.</description><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLw0AURgdRbH1sXcosRUidd5KllPqAqsXHOkwmd2xKkqkziVJ_vSmp7lzdy-V8H9yD0BklE0oYvdIm6LqcqJwowuM9NKapEFHCJNv_24UYoaMQVoQozog8RCMWK6aUEGNUP7pPqPADtEtXBOwsXnhXdKZs3vHcfUXPYCswrW4M4KnTbX8P-K0tq_J7i7xsGvDvZWhLg2fW9uTQ4apNDR4vljoAfoG19n3UNSfowOoqwOluHqO3m9nr9C6aP93eT6_nkeactBGVJuc5kZwXFnQqYyaYpEbpWJDCaqEUSRUUhUxUntiEpyrnpGA8jikzghF-jC6G3rV3Hx2ENqvLYKCqdAOuCxlNuOSSxFz16GRAjXcheLDZ2pe19puMkmyrOBsUZzvFfeB8193lNRR_-K_THrgcgD6YrVznm_7V_9p-ADx3hqY</recordid><startdate>20161005</startdate><enddate>20161005</enddate><creator>Giles, Spencer L</creator><creator>Heller, Nicholas W. M</creator><creator>Clayton, Clive R</creator><creator>Walker, Mark E</creator><creator>Wytiaz, Mark J</creator><creator>Wynne, James H</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20161005</creationdate><title>Novel Methods of Producing Low-Reflectance Coatings Utilizing Synergistic Effects of Polymer Phase Separation</title><author>Giles, Spencer L ; Heller, Nicholas W. M ; Clayton, Clive R ; Walker, Mark E ; Wytiaz, Mark J ; Wynne, James H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a330t-15cb3b0533dfea95724251c6a740dfa466096edd586b8f8396b30d237712c4203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Giles, Spencer L</creatorcontrib><creatorcontrib>Heller, Nicholas W. M</creatorcontrib><creatorcontrib>Clayton, Clive R</creatorcontrib><creatorcontrib>Walker, Mark E</creatorcontrib><creatorcontrib>Wytiaz, Mark J</creatorcontrib><creatorcontrib>Wynne, James H</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ACS applied materials & interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Giles, Spencer L</au><au>Heller, Nicholas W. M</au><au>Clayton, Clive R</au><au>Walker, Mark E</au><au>Wytiaz, Mark J</au><au>Wynne, James H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel Methods of Producing Low-Reflectance Coatings Utilizing Synergistic Effects of Polymer Phase Separation</atitle><jtitle>ACS applied materials & interfaces</jtitle><addtitle>ACS Appl. Mater. Interfaces</addtitle><date>2016-10-05</date><risdate>2016</risdate><volume>8</volume><issue>39</issue><spage>26251</spage><epage>26257</epage><pages>26251-26257</pages><issn>1944-8244</issn><eissn>1944-8252</eissn><abstract>Novel methods were developed to generate and characterize surface structures formed from polymer segregation within a powder coating system. A blend of unique acrylic polyol resins and low concentrations of matting agent afforded a durable coating exhibiting consistent low reflectance. An enhanced synergistic effect was observed from the phase separation and domain formation of the two polymeric resins with varying pendent hydroxyl group functionality and the incorporated matting agents. Together the domains and incorporated matting agents produced a significantly lower reflectance coating than the matting agent in combination with either polymeric resin alone. The rigorous thermal, optical, and spectroscopic analysis of the pigmented coating and control coatings culminated in the complete characterization of polymeric phases within the resulting coatings. Raman analysis of the control coatings via a distinct spectroscopic handle allowed for positive identification of the segregated polymer resins within the coating structure. Domains observed by optical microscopy within the control coating structure were chemically identified via Raman analysis as the high-hydroxyl content resin. Subsequent Raman mapping of the peak intensity over an entire cross-section provided consistent evidence for positive identification of the polymeric composition within the domain.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>27626644</pmid><doi>10.1021/acsami.6b06037</doi><tpages>7</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1944-8244 |
ispartof | ACS applied materials & interfaces, 2016-10, Vol.8 (39), p.26251-26257 |
issn | 1944-8244 1944-8252 |
language | eng |
recordid | cdi_proquest_miscellaneous_1835350736 |
source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
title | Novel Methods of Producing Low-Reflectance Coatings Utilizing Synergistic Effects of Polymer Phase Separation |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T22%3A36%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Novel%20Methods%20of%20Producing%20Low-Reflectance%20Coatings%20Utilizing%20Synergistic%20Effects%20of%20Polymer%20Phase%20Separation&rft.jtitle=ACS%20applied%20materials%20&%20interfaces&rft.au=Giles,%20Spencer%20L&rft.date=2016-10-05&rft.volume=8&rft.issue=39&rft.spage=26251&rft.epage=26257&rft.pages=26251-26257&rft.issn=1944-8244&rft.eissn=1944-8252&rft_id=info:doi/10.1021/acsami.6b06037&rft_dat=%3Cproquest_cross%3E1835350736%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a330t-15cb3b0533dfea95724251c6a740dfa466096edd586b8f8396b30d237712c4203%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1835350736&rft_id=info:pmid/27626644&rfr_iscdi=true |