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Tailoring Nucleation at Two Interfaces Enables Single Crystalline NiO Nanowires via Vapor–Liquid–Solid Route

Here we show a rational strategy to fabricate single crystalline NiO nanowires via a vapor–liquid–solid (VLS) route, which essentially allows us to tailor the diameter and the spatial position. Our strategy is based on the suppression of the nucleation at vapor–solid (VS) interface, which promotes n...

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Published in:ACS applied materials & interfaces 2016-10, Vol.8 (41), p.27892-27899
Main Authors: Nagashima, Kazuki, Yoshida, Hideto, Klamchuen, Annop, Kanai, Masaki, Meng, Gang, Zhuge, Fuwei, He, Yong, Anzai, Hiroshi, Zhu, Zetao, Suzuki, Masaru, Boudot, Mickaël, Takeda, Seiji, Yanagida, Takeshi
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container_end_page 27899
container_issue 41
container_start_page 27892
container_title ACS applied materials & interfaces
container_volume 8
creator Nagashima, Kazuki
Yoshida, Hideto
Klamchuen, Annop
Kanai, Masaki
Meng, Gang
Zhuge, Fuwei
He, Yong
Anzai, Hiroshi
Zhu, Zetao
Suzuki, Masaru
Boudot, Mickaël
Takeda, Seiji
Yanagida, Takeshi
description Here we show a rational strategy to fabricate single crystalline NiO nanowires via a vapor–liquid–solid (VLS) route, which essentially allows us to tailor the diameter and the spatial position. Our strategy is based on the suppression of the nucleation at vapor–solid (VS) interface, which promotes nucleation only at the liquid–solid (LS) interface. Manipulating both the supplied material fluxes (oxygen and metal) and the growth temperature enables enhancement of the nucleation only at the LS interface. Furthermore, this strategy allows us to reduce the growth temperature of single crystalline NiO nanowires down to 550 °C, which is the lowest growth temperature so far reported.
doi_str_mv 10.1021/acsami.6b09761
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title Tailoring Nucleation at Two Interfaces Enables Single Crystalline NiO Nanowires via Vapor–Liquid–Solid Route
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