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Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex
Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo...
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| Published in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2016-01, Vol.4 (3), p.497-53 |
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| Main Authors: | , , , , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c388t-1e5b1d2132cfbc518b3b88297889e0d3844dde254340f78999ea2ff4aeb8edd3 |
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| cites | cdi_FETCH-LOGICAL-c388t-1e5b1d2132cfbc518b3b88297889e0d3844dde254340f78999ea2ff4aeb8edd3 |
| container_end_page | 53 |
| container_issue | 3 |
| container_start_page | 497 |
| container_title | Journal of materials chemistry. C, Materials for optical and electronic devices |
| container_volume | 4 |
| creator | Efremova, Olga A Brylev, Konstantin A Vorotnikov, Yuri A Vejsadová, Lucie Shestopalov, Michael A Chimonides, Gwen F Mikes, Petr Topham, Paul D Kim, Sung-Jin Kitamura, Noboru Sutherland, Andrew J |
| description | Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo
6
I
8
}(OTs)
6
]
2−
(where OTs
−
is the
p
-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)
2
[{Mo
6
I
8
}(OTs)
6
], where dMDAEMA
+
is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.
Transparent yet photoluminescent, materials with facile processability are key in many applications. |
| doi_str_mv | 10.1039/c5tc03204k |
| format | article |
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6
I
8
}(OTs)
6
]
2−
(where OTs
−
is the
p
-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)
2
[{Mo
6
I
8
}(OTs)
6
], where dMDAEMA
+
is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.
Transparent yet photoluminescent, materials with facile processability are key in many applications.</description><identifier>ISSN: 2050-7526</identifier><identifier>EISSN: 2050-7534</identifier><identifier>DOI: 10.1039/c5tc03204k</identifier><language>eng</language><subject>Clusters ; Copolymerization ; Emissivity ; Metal clusters ; Molybdenum ; Photoluminescence ; Polymethyl methacrylates ; Resultants</subject><ispartof>Journal of materials chemistry. C, Materials for optical and electronic devices, 2016-01, Vol.4 (3), p.497-53</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c388t-1e5b1d2132cfbc518b3b88297889e0d3844dde254340f78999ea2ff4aeb8edd3</citedby><cites>FETCH-LOGICAL-c388t-1e5b1d2132cfbc518b3b88297889e0d3844dde254340f78999ea2ff4aeb8edd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Efremova, Olga A</creatorcontrib><creatorcontrib>Brylev, Konstantin A</creatorcontrib><creatorcontrib>Vorotnikov, Yuri A</creatorcontrib><creatorcontrib>Vejsadová, Lucie</creatorcontrib><creatorcontrib>Shestopalov, Michael A</creatorcontrib><creatorcontrib>Chimonides, Gwen F</creatorcontrib><creatorcontrib>Mikes, Petr</creatorcontrib><creatorcontrib>Topham, Paul D</creatorcontrib><creatorcontrib>Kim, Sung-Jin</creatorcontrib><creatorcontrib>Kitamura, Noboru</creatorcontrib><creatorcontrib>Sutherland, Andrew J</creatorcontrib><title>Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex</title><title>Journal of materials chemistry. C, Materials for optical and electronic devices</title><description>Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo
6
I
8
}(OTs)
6
]
2−
(where OTs
−
is the
p
-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)
2
[{Mo
6
I
8
}(OTs)
6
], where dMDAEMA
+
is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.
Transparent yet photoluminescent, materials with facile processability are key in many applications.</description><subject>Clusters</subject><subject>Copolymerization</subject><subject>Emissivity</subject><subject>Metal clusters</subject><subject>Molybdenum</subject><subject>Photoluminescence</subject><subject>Polymethyl methacrylates</subject><subject>Resultants</subject><issn>2050-7526</issn><issn>2050-7534</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpFkM9LwzAUx4MoOOYu3oUcRagmTdKlx1H8hRvusHtJk1fbmTQzacX991Yn813e48uHL48PQpeU3FLC8jstek1YSvj7CZqkRJBkLhg_Pd5pdo5mMW7JOJJmMssnaLtufO_t4NoOooaux071EFplI65UBIN9h9er1QKrzmCFm_atsfsEXBtj-wnY6141YIKy2Hm7rwx0g8MO-jHQdohjF9be7Sx8XaCzeqyF2d-eos3D_aZ4Spavj8_FYploJmWfUBAVNSllqa4rLaisWCVlms-lzIEYJjk3BlLBGSf1XOZ5Diqta66gkmAMm6LrQ-0u-I8BYl-Ov2qwVnXgh1hSyYTIuBRkRG8OqA4-xgB1uQutU2FfUlL-KC0LsSl-lb6M8NUBDlEfuX_l7BtfNnS5</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Efremova, Olga A</creator><creator>Brylev, Konstantin A</creator><creator>Vorotnikov, Yuri A</creator><creator>Vejsadová, Lucie</creator><creator>Shestopalov, Michael A</creator><creator>Chimonides, Gwen F</creator><creator>Mikes, Petr</creator><creator>Topham, Paul D</creator><creator>Kim, Sung-Jin</creator><creator>Kitamura, Noboru</creator><creator>Sutherland, Andrew J</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex</title><author>Efremova, Olga A ; Brylev, Konstantin A ; Vorotnikov, Yuri A ; Vejsadová, Lucie ; Shestopalov, Michael A ; Chimonides, Gwen F ; Mikes, Petr ; Topham, Paul D ; Kim, Sung-Jin ; Kitamura, Noboru ; Sutherland, Andrew J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c388t-1e5b1d2132cfbc518b3b88297889e0d3844dde254340f78999ea2ff4aeb8edd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Clusters</topic><topic>Copolymerization</topic><topic>Emissivity</topic><topic>Metal clusters</topic><topic>Molybdenum</topic><topic>Photoluminescence</topic><topic>Polymethyl methacrylates</topic><topic>Resultants</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Efremova, Olga A</creatorcontrib><creatorcontrib>Brylev, Konstantin A</creatorcontrib><creatorcontrib>Vorotnikov, Yuri A</creatorcontrib><creatorcontrib>Vejsadová, Lucie</creatorcontrib><creatorcontrib>Shestopalov, Michael A</creatorcontrib><creatorcontrib>Chimonides, Gwen F</creatorcontrib><creatorcontrib>Mikes, Petr</creatorcontrib><creatorcontrib>Topham, Paul D</creatorcontrib><creatorcontrib>Kim, Sung-Jin</creatorcontrib><creatorcontrib>Kitamura, Noboru</creatorcontrib><creatorcontrib>Sutherland, Andrew J</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Efremova, Olga A</au><au>Brylev, Konstantin A</au><au>Vorotnikov, Yuri A</au><au>Vejsadová, Lucie</au><au>Shestopalov, Michael A</au><au>Chimonides, Gwen F</au><au>Mikes, Petr</au><au>Topham, Paul D</au><au>Kim, Sung-Jin</au><au>Kitamura, Noboru</au><au>Sutherland, Andrew J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex</atitle><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>4</volume><issue>3</issue><spage>497</spage><epage>53</epage><pages>497-53</pages><issn>2050-7526</issn><eissn>2050-7534</eissn><abstract>Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo
6
I
8
}(OTs)
6
]
2−
(where OTs
−
is the
p
-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)
2
[{Mo
6
I
8
}(OTs)
6
], where dMDAEMA
+
is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.
Transparent yet photoluminescent, materials with facile processability are key in many applications.</abstract><doi>10.1039/c5tc03204k</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2050-7526 |
| ispartof | Journal of materials chemistry. C, Materials for optical and electronic devices, 2016-01, Vol.4 (3), p.497-53 |
| issn | 2050-7526 2050-7534 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1835564850 |
| source | Royal Society of Chemistry |
| subjects | Clusters Copolymerization Emissivity Metal clusters Molybdenum Photoluminescence Polymethyl methacrylates Resultants |
| title | Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex |
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