Rational synthesis of a novel 3,3,5-c polyhedral metal-organic framework with high thermal stability and hydrogen storage capability

By using a functionalized ligand strategy, a novel (3,3,5)-c polyhedron-based metal-organic framework ( GDMU-2 ) with high thermal stability has been constructed. GDMU-2 shows a high H 2 uptake of 240.7 cm 3 g −1 (2.16 wt%) at 77 K and 1 bar, and also exhibits a good selective adsorption of CO 2 ove...

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Bibliographic Details
Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2016-01, Vol.4 (3), p.1163-11634
Main Authors: Liu, Jianqiang, Liu, Guoliang, Gu, Chuying, Liu, Weicong, Xu, Jingwen, Li, Baohong, Wang, Wenjing
Format: Article
Language:English
Subjects:
Carbon dioxide
Ligands
Metal-organic frameworks
Renewable energy
Strategy
Synthesis
Thermal stability
Uptakes
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Summary:By using a functionalized ligand strategy, a novel (3,3,5)-c polyhedron-based metal-organic framework ( GDMU-2 ) with high thermal stability has been constructed. GDMU-2 shows a high H 2 uptake of 240.7 cm 3 g −1 (2.16 wt%) at 77 K and 1 bar, and also exhibits a good selective adsorption of CO 2 over N 2 and CH 4 . By using a functionalized ligand strategy, an uncommon (3,3,5)-c polyhedron-based metal-organic framework named GDMU-2 has been constructed, which has a high H 2 uptake of 240.7 cm 3 g −1 (2.16 wt%) at 77 K and 1 bar.
ISSN:2050-7488
2050-7496
DOI:10.1039/c6ta03675a