MoS2 supported single platinum atoms and their superior catalytic activity for CO oxidation: a density functional theory study

Late transition metals, such as Rh, Ir, Pd and Pt, have a strong tendency to form a square-planar 16-electron complex. Although this feature has been widely used in organometallics to develop homogeneous catalysts, a single-atom heterogeneous analogue has not yet been reported. In this work, we show...

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Bibliographic Details
Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-01, Vol.3 (46), p.23113-23119
Main Authors: Du, Chunmiao, Lin, Haiping, Lin, Bin, Ma, Zeyao, Hou, Tingjun, Tang, Jianxin, Li, Youyong
Format: Article
Language:English
Subjects:
Anchoring
Catalysis
Catalysts
Cobalt
Molybdenum disulfide
Oxidation
Platinum
Surface chemistry
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Summary:Late transition metals, such as Rh, Ir, Pd and Pt, have a strong tendency to form a square-planar 16-electron complex. Although this feature has been widely used in organometallics to develop homogeneous catalysts, a single-atom heterogeneous analogue has not yet been reported. In this work, we show that a 16-electron complex may act as an important transition state in the CO oxidation over a single Pt atom supported by a MoS2 monolayer (Pt/MoS2). The catalytic oxidation reaction prefers to start with the Langmuir-Hinshelwood (L-H) reaction, where the CO and O2 molecules are first co-adsorbed on the Pt atom, then cross a small barrier of 0.40 eV to form a square-planar 16-electron intermediate state, and subsequently the first CO2 is released. The activation barrier of the following Eley-Rideal (E-R) reaction is only 0.23 eV. The superior catalytic reactivity of the Pt/MoS2 surface can be explained by the quantum confinement effect of the Pt-5d orbitals and the stability of the square-planar 16-electron transition state. In addition, MoS2 may serve as a defect-free two dimensional anchoring substrate for Pt atomic adsorption. It provides not only a very large surface-to-volume ratio, but also a well-defined structure with a uniform distribution of anchoring points. The square-planar 16-electron intermediate state of the L-H reaction, together with the new MoS2 anchoring substrate, may provide a new opportunity for the design of single-atom catalysts on two-dimensional surfaces.
ISSN:2050-7488
2050-7496
DOI:10.1039/c5ta05084g