Cobalt-Catalyzed Direct Amination of Arenes with Alkylamines via Bidentate-Chelation Assistance

Cobalt‐catalyzed C−H amination of arenes with alkylamines by the assistance of 8‐aminoquinoline as auxiliary through sp2 C−H bond functionalization has been achieved. Attractive features of this protocol include the low loading of the cobalt catalyst and the readily available reagents.

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2016-08, Vol.358 (16), p.2707-2711
Main Authors: Yan, Qiangqiang, Xiao, Tangxin, Liu, Zhanxiang, Zhang, Yuhong
Format: Article
Language:English
Subjects:
8-aminoquinoline as auxiliary
Alkylamines
Aromatic compounds
Bonding
Catalysis
Catalysts
Cobalt
C−H amination
Reagents
Synthesis
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Description
Summary:Cobalt‐catalyzed C−H amination of arenes with alkylamines by the assistance of 8‐aminoquinoline as auxiliary through sp2 C−H bond functionalization has been achieved. Attractive features of this protocol include the low loading of the cobalt catalyst and the readily available reagents.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201600282