The first porphyrin-subphthalocyaninatoboron(iii)-fused hybrid with unique conformation and intramolecular charge transfer behavior

Porphyrin and subphthalocyaninatoboron(iii) chromophores have been fused through a quinoxaline moiety, resulting in the first porphyrin-subphthalocyaninatoboron(iii)-fused hybrid with intramolecular charge transfer from tetrapyrrole/tripyrrole chromophores to the quinoxaline moiety. The unique plane...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (69), p.10517-10520
Main Authors: Zhang, Yuehong, Oh, Juwon, Wang, Kang, Shin, Dongju, Zhan, Xiaopeng, Zheng, Yingting, Kim, Dongho, Jiang, Jianzhuang
Format: Article
Language:English
Subjects:
Charge transfer
Chromophores
Diffraction
Molecular structure
Porphyrins
Quinoxalines
Single crystals
X-rays
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Summary:Porphyrin and subphthalocyaninatoboron(iii) chromophores have been fused through a quinoxaline moiety, resulting in the first porphyrin-subphthalocyaninatoboron(iii)-fused hybrid with intramolecular charge transfer from tetrapyrrole/tripyrrole chromophores to the quinoxaline moiety. The unique plane-bowl molecular structure of this hybrid was revealed based on single crystal X-ray diffraction analysis for the first time.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc05383a