Design of Visible Light Sensitive Heterogeneous Photocatalyst by Utilization of Sulfocalixarene as a Linker of Zinc Porphyrin and Pt-TiO2

Visible light sensitive heterogeneous photocatalyst was successfully designed by utilization of 4-sulfocalix[4]arene as a linker molecule for stable immobilization of 5,10,15,20-tetrakis(1-methyl-pyridinium-4-yl)porphyrinatozinc(II) ion on Pt-loaded TiO2. This heterogeneous system can act as an effi...

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Bibliographic Details
Published in:Bulletin of the Chemical Society of Japan 2016-07, Vol.89 (7), p.743-745
Main Authors: Kamegawa, Takashi, Imai, Hiroki, Yamashita, Hiromi
Format: Article
Language:English
Subjects:
Control systems
Design engineering
Photocatalysis
Photocatalysts
Porphyrins
Titanium dioxide
Utilization
Zinc
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Summary:Visible light sensitive heterogeneous photocatalyst was successfully designed by utilization of 4-sulfocalix[4]arene as a linker molecule for stable immobilization of 5,10,15,20-tetrakis(1-methyl-pyridinium-4-yl)porphyrinatozinc(II) ion on Pt-loaded TiO2. This heterogeneous system can act as an efficient photocatalyst for generation of H2 under controlled reaction conditions.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20160080