Design and synthesis of hyperstructured molecules based on cyclophosphazene core for multiphoton absorption

• Published in: Materials chemistry and physics 2016-09, Vol.180, p.38-45
• Main Authors: Naik, K. Praveen Kumar, Sreeramulu, V., Ramya, E., Muralidharan, K., Rao, D. Narayana
• Format: Article
• Language: English
• Subjects: Absorption; Constraining; Cross sections; Cyclophosphazene; Femtosecond; Hyperstructured molecules; Lasers; Multiphoton absorption; NLO properties; Nonlinearity; Optical properties; Phosphazene materials; Spectra; Z-scan technique
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2016.05.020

Cyclophosphazene based hyperstructured molecules were synthesized through simple nucleophilic substitution reactions. All these molecules were characterized by multinuclear NMR, MALDI and HRMS spectral data. Third order nonlinear optical properties of the hyperstructured molecules were measured using Z-scan technique with 532 nm, picosecond (ps) laser and 800 nm, femtosecond (fs) laser pulses. The molecules showed reverse saturable absorption on excitation at both 532 nm and 800 nm, which could be attributed to the two-photon absorption (2 PA) and three-photon absorption (3 PA), respectively. The 2 PA and 3 PA cross section values exhibited by the molecules based on cyclophosphazene are as high as 527 GM and 1.86 × 10−76 cm−6 s2 photon−1, respectively. The 2PA, 3PA coefficients and optical limiting properties make them suitable candidates for nonlinear optical devices in the visible and near IR range. The hyperstructured molecules based on cyclophosphazene core were synthesized and used for multiphoton absorption. Open aperture Z-scan curves of hyper structured molecules at the excitation of (a) picosecond laser and (b) femtosecond laser representing multiphoton absorption properties are reported. [Display omitted] •Two hyperstructured molecules based on cyclophosphazene core are designed for multiphoton absorption.•NLO properties are measured using Z-scan technique at 532 nm and 800 nm wavelengths.•The molecules were tested for the optical limiting applications at 532 nm and 800 nm laser pulses.