Nickel oxide-deposited cellulose/CNT composite electrode for non-enzymatic urea detection

• Published in: Sensors and actuators. B, Chemical Chemical, 2016-11, Vol.236, p.304-310
• Main Authors: Nguyen, Nhi Sa, Yoon, Hyon Hee
• Format: Article
• Language: English
• Subjects: Carbon nanotube; Carbon nanotubes; Cellulose; Electrodes; Glass; Indium tin oxide; Nickel; Nickel oxide; Non-enzymatic; Sensors; Urea sensor; Ureas
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2016.05.165

A highly sensitive non-enzymatic urea sensor was fabricated using nickel oxide deposited on a cellulose/carbon nanotube composite. [Display omitted] •NiO nano particles were impregnated onto cellulose/CNT composite for the electro-oxidation of urea.•The simply prepared NiO/Cellulose/CNT electrode exhibited remarkably high sensitivity.•The sensor showed a high stability and feasibility for urea analysis in urine sample. A highly sensitive non-enzymatic urea sensor was fabricated using nickel oxide deposited on a cellulose/carbon nanotube (CNT) composite. The structure and morphological properties of the NiO/cellulose/CNT composite were investigated using X-ray diffraction and scanning electron microscopy. A thin film of the NiO/cellulose/CNT composite was coated on an indium tin oxide glass to fabricate an amperometric urea sensor. The composition of the modified electrode and detection conditions (i.e., pH and temperature) were optimized. The prepared electrode exhibited an excellent sensitivity of 371μAmM−1cm−2 with a fast response time of 4s. The electrode also showed high stability with only a 3.6% decrease in its sensitivity after storage for two months under ambient conditions. In addition, the feasibility for urea analysis in urine samples was demonstrated.