The UiO-66-SO3H metal-organic framework as a green catalyst for the facile synthesis of dihydro-2-oxypyrrole derivatives

The multicomponent domino reaction synthesis of dihydro-2-oxopyrroles has been performed using the sulfonated metal-organic framework, UiO-66-SO3H (UiO is the University of Oslo), as a highly efficient acid catalyst. The MOF can act as both Broensted (H+) and Lewis acid (Zr4+) active sites. The prot...

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Bibliographic Details
Published in:RSC advances 2016-01, Vol.6 (35), p.29182-29189
Main Authors: Ghorbani-Vaghei, Ramin, Azarifar, Daliran, Saba, Oveisi, Ali Reza
Format: Article
Language:English
Subjects:
Cascade chemical reactions
Catalysts
Derivatives
Lewis acid
Metal-organic frameworks
Synthesis
Synthesis (chemistry)
Online Access:Get full text
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Summary:The multicomponent domino reaction synthesis of dihydro-2-oxopyrroles has been performed using the sulfonated metal-organic framework, UiO-66-SO3H (UiO is the University of Oslo), as a highly efficient acid catalyst. The MOF can act as both Broensted (H+) and Lewis acid (Zr4+) active sites. The protocol presents an environmentally benign as well as a simple experimental and work-up procedure.
ISSN:2046-2069
DOI:10.1039/c6ra00463f