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Metal-Organic Framework for Emulsifying Carbon Dioxide and Water
Forming emulsions of carbon dioxide (CO2) and water can largely expand the utility of CO2. Herein we propose for the first time the utilization of a metal–organic framework (MOF) for emulsifying CO2 and water. Owing to the hybrid composition, MOF particles can easily assemble at the CO2/water interf...
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| Published in: | Angewandte Chemie 2016-09, Vol.128 (38), p.11544-11548 |
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| Main Authors: | , , , , , , , , , |
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| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c2330-f98d8206c354951698b092239a48b0f2b30dd6f6bad0c489ab9f94f623ad85373 |
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| cites | cdi_FETCH-LOGICAL-c2330-f98d8206c354951698b092239a48b0f2b30dd6f6bad0c489ab9f94f623ad85373 |
| container_end_page | 11548 |
| container_issue | 38 |
| container_start_page | 11544 |
| container_title | Angewandte Chemie |
| container_volume | 128 |
| creator | Liu, Chengcheng Zhang, Jianling Zheng, Lirong Zhang, Jing Sang, Xinxin Kang, Xinchen Zhang, Bingxing Luo, Tian Tan, Xiuniang Han, Buxing |
| description | Forming emulsions of carbon dioxide (CO2) and water can largely expand the utility of CO2. Herein we propose for the first time the utilization of a metal–organic framework (MOF) for emulsifying CO2 and water. Owing to the hybrid composition, MOF particles can easily assemble at the CO2/water interface to create a rigid protective barrier around the dispersed droplet. The MOF‐stabilized CO2 and water emulsion has exceptional stability compared to those emulsions stabilized by surfactants or other solids. Moreover, the CO2 and water emulsion stabilized by MOF is “tunable” due to the designable features of MOFs and adjustable character of CO2. Such a novel kind of emulsion composed of CO2, water, and MOF provides a facile route for constructing MOF superstructures with many advantages. The macroporous networks and hollow capsules of different kinds of MOFs have been successfully derived from CO2 and water emulsions.
MOFs als Emulgatoren: Metall‐organische Gerüste (MOFs) wurden zum Emulgieren von CO2 und Wasser eingesetzt. Die MOF‐stabilisierte CO2‐Wasser‐Emulsion ist außergewöhnlich stabil und lässt sich durch Variieren des MOF und der Lösungseigenschaften von CO2 gezielt einstellen. Die Freisetzung von CO2 aus der Emulsion bietet eine einfache Möglichkeit zum Aufbau neuartiger MOF‐Überstrukturen. |
| doi_str_mv | 10.1002/ange.201602150 |
| format | article |
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MOFs als Emulgatoren: Metall‐organische Gerüste (MOFs) wurden zum Emulgieren von CO2 und Wasser eingesetzt. Die MOF‐stabilisierte CO2‐Wasser‐Emulsion ist außergewöhnlich stabil und lässt sich durch Variieren des MOF und der Lösungseigenschaften von CO2 gezielt einstellen. Die Freisetzung von CO2 aus der Emulsion bietet eine einfache Möglichkeit zum Aufbau neuartiger MOF‐Überstrukturen.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.201602150</identifier><language>eng</language><publisher>Weinheim: Blackwell Publishing Ltd</publisher><subject>Aquatic plants ; Carbon dioxide ; Chemistry ; CO2 ; Dispersion ; Droplets ; Emulsification ; Emulsionen ; Emulsions ; Forming ; H2O ; Metal-organic frameworks ; Metall-organische Gerüste ; Metals ; Mud-water interfaces ; Networks ; Particulates ; Pollutants ; Routing (telecommunications) ; Solids ; Stability ; Superstructures ; Surfactants ; Water utilities ; Überstrukturen</subject><ispartof>Angewandte Chemie, 2016-09, Vol.128 (38), p.11544-11548</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2330-f98d8206c354951698b092239a48b0f2b30dd6f6bad0c489ab9f94f623ad85373</citedby><cites>FETCH-LOGICAL-c2330-f98d8206c354951698b092239a48b0f2b30dd6f6bad0c489ab9f94f623ad85373</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Liu, Chengcheng</creatorcontrib><creatorcontrib>Zhang, Jianling</creatorcontrib><creatorcontrib>Zheng, Lirong</creatorcontrib><creatorcontrib>Zhang, Jing</creatorcontrib><creatorcontrib>Sang, Xinxin</creatorcontrib><creatorcontrib>Kang, Xinchen</creatorcontrib><creatorcontrib>Zhang, Bingxing</creatorcontrib><creatorcontrib>Luo, Tian</creatorcontrib><creatorcontrib>Tan, Xiuniang</creatorcontrib><creatorcontrib>Han, Buxing</creatorcontrib><title>Metal-Organic Framework for Emulsifying Carbon Dioxide and Water</title><title>Angewandte Chemie</title><addtitle>Angew. Chem</addtitle><description>Forming emulsions of carbon dioxide (CO2) and water can largely expand the utility of CO2. Herein we propose for the first time the utilization of a metal–organic framework (MOF) for emulsifying CO2 and water. Owing to the hybrid composition, MOF particles can easily assemble at the CO2/water interface to create a rigid protective barrier around the dispersed droplet. The MOF‐stabilized CO2 and water emulsion has exceptional stability compared to those emulsions stabilized by surfactants or other solids. Moreover, the CO2 and water emulsion stabilized by MOF is “tunable” due to the designable features of MOFs and adjustable character of CO2. Such a novel kind of emulsion composed of CO2, water, and MOF provides a facile route for constructing MOF superstructures with many advantages. The macroporous networks and hollow capsules of different kinds of MOFs have been successfully derived from CO2 and water emulsions.
MOFs als Emulgatoren: Metall‐organische Gerüste (MOFs) wurden zum Emulgieren von CO2 und Wasser eingesetzt. Die MOF‐stabilisierte CO2‐Wasser‐Emulsion ist außergewöhnlich stabil und lässt sich durch Variieren des MOF und der Lösungseigenschaften von CO2 gezielt einstellen. Die Freisetzung von CO2 aus der Emulsion bietet eine einfache Möglichkeit zum Aufbau neuartiger MOF‐Überstrukturen.</description><subject>Aquatic plants</subject><subject>Carbon dioxide</subject><subject>Chemistry</subject><subject>CO2</subject><subject>Dispersion</subject><subject>Droplets</subject><subject>Emulsification</subject><subject>Emulsionen</subject><subject>Emulsions</subject><subject>Forming</subject><subject>H2O</subject><subject>Metal-organic frameworks</subject><subject>Metall-organische Gerüste</subject><subject>Metals</subject><subject>Mud-water interfaces</subject><subject>Networks</subject><subject>Particulates</subject><subject>Pollutants</subject><subject>Routing (telecommunications)</subject><subject>Solids</subject><subject>Stability</subject><subject>Superstructures</subject><subject>Surfactants</subject><subject>Water utilities</subject><subject>Überstrukturen</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkU1Lw0AQhhdRsFavngNevKTOfmdvSm2jUC3SSsHLskl2y2qa6G6L9t8bqYh48TRzeJ5heF-ETjEMMAC5MM3SDghgAQRz2EM9zAlOqeRyH_UAGEszwtQhOorxGQAEkaqHLu_s2tTpNCxN48tkHMzKvrfhJXFtSEarTR292_pmmQxNKNomufbth69sYpoqWZi1DcfowJk62pPv2UeP49F8eJNOpvnt8GqSloRSSJ3KqoyAKClnimOhsgIUIVQZ1m2OFBSqSjhRmApKlilTKKeYE4SaKuNU0j463919De3bxsa1XvlY2ro2jW03UeOMcsGJlKRDz_6gz-0mNN13GiuQHCTDvKMGO6oMbYzBOv0a_MqErcagvwLVX4Hqn0A7Qe2Ed1_b7T-0vrrPR7_ddOf6uLYfP64JL1rIriK9uM_1nOWz7GH2pBX9BI8mhqY</recordid><startdate>20160912</startdate><enddate>20160912</enddate><creator>Liu, Chengcheng</creator><creator>Zhang, Jianling</creator><creator>Zheng, Lirong</creator><creator>Zhang, Jing</creator><creator>Sang, Xinxin</creator><creator>Kang, Xinchen</creator><creator>Zhang, Bingxing</creator><creator>Luo, Tian</creator><creator>Tan, Xiuniang</creator><creator>Han, Buxing</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160912</creationdate><title>Metal-Organic Framework for Emulsifying Carbon Dioxide and Water</title><author>Liu, Chengcheng ; Zhang, Jianling ; Zheng, Lirong ; Zhang, Jing ; Sang, Xinxin ; Kang, Xinchen ; Zhang, Bingxing ; Luo, Tian ; Tan, Xiuniang ; Han, Buxing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2330-f98d8206c354951698b092239a48b0f2b30dd6f6bad0c489ab9f94f623ad85373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Aquatic plants</topic><topic>Carbon dioxide</topic><topic>Chemistry</topic><topic>CO2</topic><topic>Dispersion</topic><topic>Droplets</topic><topic>Emulsification</topic><topic>Emulsionen</topic><topic>Emulsions</topic><topic>Forming</topic><topic>H2O</topic><topic>Metal-organic frameworks</topic><topic>Metall-organische Gerüste</topic><topic>Metals</topic><topic>Mud-water interfaces</topic><topic>Networks</topic><topic>Particulates</topic><topic>Pollutants</topic><topic>Routing (telecommunications)</topic><topic>Solids</topic><topic>Stability</topic><topic>Superstructures</topic><topic>Surfactants</topic><topic>Water utilities</topic><topic>Überstrukturen</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Chengcheng</creatorcontrib><creatorcontrib>Zhang, Jianling</creatorcontrib><creatorcontrib>Zheng, Lirong</creatorcontrib><creatorcontrib>Zhang, Jing</creatorcontrib><creatorcontrib>Sang, Xinxin</creatorcontrib><creatorcontrib>Kang, Xinchen</creatorcontrib><creatorcontrib>Zhang, Bingxing</creatorcontrib><creatorcontrib>Luo, Tian</creatorcontrib><creatorcontrib>Tan, Xiuniang</creatorcontrib><creatorcontrib>Han, Buxing</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Chengcheng</au><au>Zhang, Jianling</au><au>Zheng, Lirong</au><au>Zhang, Jing</au><au>Sang, Xinxin</au><au>Kang, Xinchen</au><au>Zhang, Bingxing</au><au>Luo, Tian</au><au>Tan, Xiuniang</au><au>Han, Buxing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal-Organic Framework for Emulsifying Carbon Dioxide and Water</atitle><jtitle>Angewandte Chemie</jtitle><addtitle>Angew. Chem</addtitle><date>2016-09-12</date><risdate>2016</risdate><volume>128</volume><issue>38</issue><spage>11544</spage><epage>11548</epage><pages>11544-11548</pages><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>Forming emulsions of carbon dioxide (CO2) and water can largely expand the utility of CO2. Herein we propose for the first time the utilization of a metal–organic framework (MOF) for emulsifying CO2 and water. Owing to the hybrid composition, MOF particles can easily assemble at the CO2/water interface to create a rigid protective barrier around the dispersed droplet. The MOF‐stabilized CO2 and water emulsion has exceptional stability compared to those emulsions stabilized by surfactants or other solids. Moreover, the CO2 and water emulsion stabilized by MOF is “tunable” due to the designable features of MOFs and adjustable character of CO2. Such a novel kind of emulsion composed of CO2, water, and MOF provides a facile route for constructing MOF superstructures with many advantages. The macroporous networks and hollow capsules of different kinds of MOFs have been successfully derived from CO2 and water emulsions.
MOFs als Emulgatoren: Metall‐organische Gerüste (MOFs) wurden zum Emulgieren von CO2 und Wasser eingesetzt. Die MOF‐stabilisierte CO2‐Wasser‐Emulsion ist außergewöhnlich stabil und lässt sich durch Variieren des MOF und der Lösungseigenschaften von CO2 gezielt einstellen. Die Freisetzung von CO2 aus der Emulsion bietet eine einfache Möglichkeit zum Aufbau neuartiger MOF‐Überstrukturen.</abstract><cop>Weinheim</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/ange.201602150</doi><tpages>5</tpages></addata></record> |
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| subjects | Aquatic plants Carbon dioxide Chemistry CO2 Dispersion Droplets Emulsification Emulsionen Emulsions Forming H2O Metal-organic frameworks Metall-organische Gerüste Metals Mud-water interfaces Networks Particulates Pollutants Routing (telecommunications) Solids Stability Superstructures Surfactants Water utilities Überstrukturen |
| title | Metal-Organic Framework for Emulsifying Carbon Dioxide and Water |
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