Efficient boron abstraction using honeycomb-like porous magnetic hybrids: Assessment of techno-economic recovery of boric acid

• Published in: Journal of environmental management 2016-12, Vol.183 (Pt 3), p.917-924
• Main Authors: Oladipo, Akeem Adeyemi, Gazi, Mustafa
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Boric acid recovery; Boric Acids - isolation & purification; Boron - isolation & purification; Boron-selective adsorbents; Chemical Precipitation; Chromium - chemistry; Cost-Benefit Analysis; Desorption; Ferric Compounds - chemistry; Fixed-bed studies; Hybrid materials; Hydrogen-Ion Concentration; Kinetics; Magnetics - methods; Models, Theoretical; Nickel - chemistry; Nutrient removal; Porosity; Porous magnetic adsorbents; Porous materials; Sodium - chemistry; Techno-economic analysis; Water Pollutants, Chemical - chemistry; Water Pollutants, Chemical - isolation & purification; Water Purification - economics; Water Purification - instrumentation; Water Purification - methods; Water treatment
• ISSN: 0301-4797; 1095-8630
• DOI: 10.1016/j.jenvman.2016.09.059

Porous magnetic hybrids were synthesized and functionalized with glycidol to produce boron-selective adsorbent. The magnetic hybrid (MH) comparatively out-performed the existing expensive adsorbents. MH had a saturation magnetisation of 63.48 emu/g and average pore diameter ranging from meso to macropores. The magnetic hybrids showed excellent selectivity towards boron and resulted in 79–93% boron removal even in the presence of competing metal ions (Na+ and Cr2+). Experiments were performed in a column system, and breakthrough time was observed to increase with bed depths and decreased with flow rates. The batch experiments revealed that 60 min was enough to achieve equilibrium, and the level of boron sorption was 108.5 mg/g from a synthetic solution. Several adsorption-desorption cycles were performed using a simple acid–water treatment and evaluated using various kinetic models. The spent adsorbents could be separated easily from the mixture by an external magnetic field. The cost-benefit analysis was performed for the treatment of 72 m3/year boron effluent, including five years straight line depreciation charges of equipment. The net profit and standard percentage confirmed that the recovery process is economically feasible. •Economic porous magnetic hybrid (MH) synthesized for boron removal.•The sorption was evaluated by both batch and fixed-bed passage.•Cost-benefit analysis was performed for the treatment of 72 m3/year boron effluent.•Mathematical models were applied to describe the desorption process.•MH showed excellent selectivity towards boron in the presence of interfering ions.