Nucleophilic Transfer Reactions of the [Si(C2F5)3]− Moiety

The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)3H at low temperatures. Subsequent quenching of the resulting salt‐like compounds with suitable electrophiles, such as transition‐metal complexes or Group 14 element halides, leads to a plethora of novel tris(pent...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2016-12, Vol.55 (52), p.16161-16164
Main Authors: Schwarze, Nico, Steinhauer, Simon, Neumann, Beate, Stammler, Hans-Georg, Hoge, Berthold
Format: Article
Language:English
Subjects:
Chemical bonds
fluorine
nucleophilic transfer reactions
perfluoroalkyl compounds
silanides
silicon
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c5845-dada561225e2dcb8b750f2bf1da6fb30fac85d64310e29b3e563c37978dcc04b3
cites cdi_FETCH-LOGICAL-c5845-dada561225e2dcb8b750f2bf1da6fb30fac85d64310e29b3e563c37978dcc04b3
container_end_page 16164
container_issue 52
container_start_page 16161
container_title Angewandte Chemie International Edition
container_volume 55
creator Schwarze, Nico
Steinhauer, Simon
Neumann, Beate
Stammler, Hans-Georg
Hoge, Berthold
description The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)3H at low temperatures. Subsequent quenching of the resulting salt‐like compounds with suitable electrophiles, such as transition‐metal complexes or Group 14 element halides, leads to a plethora of novel tris(pentafluoroethyl)silane derivatives. This underlines the versatility of Li[Si(C2F5)3] as a powerful nucleophilic transfer reagent. Easily transferred: The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)3H at low temperatures. Subsequent quenching with suitable electrophiles leads to a plethora of tris(pentafluoroethyl)silane derivatives and underlines the versatility of Li[Si(C2F5)3] as a powerful nucleophilic transfer reagent of the [Si(C2F5)3]− unit.
doi_str_mv 10.1002/anie.201609575
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1845257491</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1845257491</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5845-dada561225e2dcb8b750f2bf1da6fb30fac85d64310e29b3e563c37978dcc04b3</originalsourceid><addsrcrecordid>eNqF0MtKxDAUBuAgivetSym40UXHXJqkBTcy3tERvC5EQpqeYrTTjkmLzhu49hF9EiOjg7hxlbP4zn_Cj9AawT2CMd3WtYUexUTgjEs-gxYJpyRmUrLZMCeMxTLlZAEtef8YfJpiMY8WqMzCLOgi2hl0poJm9GAra6Irp2tfgosuQJvWNrWPmjJqHyC6u7SbfXrAt9j9x9t7dNZYaMcraK7UlYfV73cZXR_sX_WP4tPzw-P-7mlseJrwuNCF5oJQyoEWJk9zyXFJ85IUWpQ5w6U2KS9EwggGmuUMuGCGyUymhTE4ydky2pzkjlzz3IFv1dB6A1Wla2g6r0i4QrlMMhLoxh_62HSuDr8LimORUZrIoHoTZVzjvYNSjZwdajdWBKuvXtVXr2raa1hY_47t8iEUU_5TZADZBLzYCsb_xKndwfH-7_B4smt9C6_TXe2elJAs8NvBoRrcnBzhS3qm9tgn522SBg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1850692247</pqid></control><display><type>article</type><title>Nucleophilic Transfer Reactions of the [Si(C2F5)3]− Moiety</title><source>Wiley</source><creator>Schwarze, Nico ; Steinhauer, Simon ; Neumann, Beate ; Stammler, Hans-Georg ; Hoge, Berthold</creator><creatorcontrib>Schwarze, Nico ; Steinhauer, Simon ; Neumann, Beate ; Stammler, Hans-Georg ; Hoge, Berthold</creatorcontrib><description>The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)3H at low temperatures. Subsequent quenching of the resulting salt‐like compounds with suitable electrophiles, such as transition‐metal complexes or Group 14 element halides, leads to a plethora of novel tris(pentafluoroethyl)silane derivatives. This underlines the versatility of Li[Si(C2F5)3] as a powerful nucleophilic transfer reagent. Easily transferred: The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)3H at low temperatures. Subsequent quenching with suitable electrophiles leads to a plethora of tris(pentafluoroethyl)silane derivatives and underlines the versatility of Li[Si(C2F5)3] as a powerful nucleophilic transfer reagent of the [Si(C2F5)3]− unit.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201609575</identifier><identifier>PMID: 27902862</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>Chemical bonds ; fluorine ; nucleophilic transfer reactions ; perfluoroalkyl compounds ; silanides ; silicon</subject><ispartof>Angewandte Chemie International Edition, 2016-12, Vol.55 (52), p.16161-16164</ispartof><rights>2016 Wiley‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><rights>2016 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim.</rights><rights>2016 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5845-dada561225e2dcb8b750f2bf1da6fb30fac85d64310e29b3e563c37978dcc04b3</citedby><cites>FETCH-LOGICAL-c5845-dada561225e2dcb8b750f2bf1da6fb30fac85d64310e29b3e563c37978dcc04b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27902862$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Schwarze, Nico</creatorcontrib><creatorcontrib>Steinhauer, Simon</creatorcontrib><creatorcontrib>Neumann, Beate</creatorcontrib><creatorcontrib>Stammler, Hans-Georg</creatorcontrib><creatorcontrib>Hoge, Berthold</creatorcontrib><title>Nucleophilic Transfer Reactions of the [Si(C2F5)3]− Moiety</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)3H at low temperatures. Subsequent quenching of the resulting salt‐like compounds with suitable electrophiles, such as transition‐metal complexes or Group 14 element halides, leads to a plethora of novel tris(pentafluoroethyl)silane derivatives. This underlines the versatility of Li[Si(C2F5)3] as a powerful nucleophilic transfer reagent. Easily transferred: The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)3H at low temperatures. Subsequent quenching with suitable electrophiles leads to a plethora of tris(pentafluoroethyl)silane derivatives and underlines the versatility of Li[Si(C2F5)3] as a powerful nucleophilic transfer reagent of the [Si(C2F5)3]− unit.</description><subject>Chemical bonds</subject><subject>fluorine</subject><subject>nucleophilic transfer reactions</subject><subject>perfluoroalkyl compounds</subject><subject>silanides</subject><subject>silicon</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqF0MtKxDAUBuAgivetSym40UXHXJqkBTcy3tERvC5EQpqeYrTTjkmLzhu49hF9EiOjg7hxlbP4zn_Cj9AawT2CMd3WtYUexUTgjEs-gxYJpyRmUrLZMCeMxTLlZAEtef8YfJpiMY8WqMzCLOgi2hl0poJm9GAra6Irp2tfgosuQJvWNrWPmjJqHyC6u7SbfXrAt9j9x9t7dNZYaMcraK7UlYfV73cZXR_sX_WP4tPzw-P-7mlseJrwuNCF5oJQyoEWJk9zyXFJ85IUWpQ5w6U2KS9EwggGmuUMuGCGyUymhTE4ydky2pzkjlzz3IFv1dB6A1Wla2g6r0i4QrlMMhLoxh_62HSuDr8LimORUZrIoHoTZVzjvYNSjZwdajdWBKuvXtVXr2raa1hY_47t8iEUU_5TZADZBLzYCsb_xKndwfH-7_B4smt9C6_TXe2elJAs8NvBoRrcnBzhS3qm9tgn522SBg</recordid><startdate>20161223</startdate><enddate>20161223</enddate><creator>Schwarze, Nico</creator><creator>Steinhauer, Simon</creator><creator>Neumann, Beate</creator><creator>Stammler, Hans-Georg</creator><creator>Hoge, Berthold</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20161223</creationdate><title>Nucleophilic Transfer Reactions of the [Si(C2F5)3]− Moiety</title><author>Schwarze, Nico ; Steinhauer, Simon ; Neumann, Beate ; Stammler, Hans-Georg ; Hoge, Berthold</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5845-dada561225e2dcb8b750f2bf1da6fb30fac85d64310e29b3e563c37978dcc04b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Chemical bonds</topic><topic>fluorine</topic><topic>nucleophilic transfer reactions</topic><topic>perfluoroalkyl compounds</topic><topic>silanides</topic><topic>silicon</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schwarze, Nico</creatorcontrib><creatorcontrib>Steinhauer, Simon</creatorcontrib><creatorcontrib>Neumann, Beate</creatorcontrib><creatorcontrib>Stammler, Hans-Georg</creatorcontrib><creatorcontrib>Hoge, Berthold</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health &amp; Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schwarze, Nico</au><au>Steinhauer, Simon</au><au>Neumann, Beate</au><au>Stammler, Hans-Georg</au><au>Hoge, Berthold</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nucleophilic Transfer Reactions of the [Si(C2F5)3]− Moiety</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2016-12-23</date><risdate>2016</risdate><volume>55</volume><issue>52</issue><spage>16161</spage><epage>16164</epage><pages>16161-16164</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)3H at low temperatures. Subsequent quenching of the resulting salt‐like compounds with suitable electrophiles, such as transition‐metal complexes or Group 14 element halides, leads to a plethora of novel tris(pentafluoroethyl)silane derivatives. This underlines the versatility of Li[Si(C2F5)3] as a powerful nucleophilic transfer reagent. Easily transferred: The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)3H at low temperatures. Subsequent quenching with suitable electrophiles leads to a plethora of tris(pentafluoroethyl)silane derivatives and underlines the versatility of Li[Si(C2F5)3] as a powerful nucleophilic transfer reagent of the [Si(C2F5)3]− unit.</abstract><cop>Germany</cop><pub>Blackwell Publishing Ltd</pub><pmid>27902862</pmid><doi>10.1002/anie.201609575</doi><tpages>4</tpages><edition>International ed. in English</edition></addata></record>
fulltext fulltext
identifier ISSN: 1433-7851
ispartof Angewandte Chemie International Edition, 2016-12, Vol.55 (52), p.16161-16164
issn 1433-7851
1521-3773
language eng
recordid cdi_proquest_miscellaneous_1845257491
source Wiley
subjects Chemical bonds
fluorine
nucleophilic transfer reactions
perfluoroalkyl compounds
silanides
silicon
title Nucleophilic Transfer Reactions of the [Si(C2F5)3]− Moiety
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-28T17%3A52%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Nucleophilic%20Transfer%20Reactions%20of%20the%20%5BSi(C2F5)3%5D%E2%88%92%20Moiety&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Schwarze,%20Nico&rft.date=2016-12-23&rft.volume=55&rft.issue=52&rft.spage=16161&rft.epage=16164&rft.pages=16161-16164&rft.issn=1433-7851&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.201609575&rft_dat=%3Cproquest_cross%3E1845257491%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c5845-dada561225e2dcb8b750f2bf1da6fb30fac85d64310e29b3e563c37978dcc04b3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1850692247&rft_id=info:pmid/27902862&rfr_iscdi=true