Manifesting the sergeants-and-soldiers principle in coadsorber induced homochiral polymorphic assemblies at the liquid/solid interface

We systematically studied the operation of coadsorber-induced surface chirality in a series of enantiomeric surface supramolecular assemblies. The correlation of chiral amplification degree with the proportion of enantiomeric interaction in the total intermolecular interaction is deduced. Strong hyd...

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Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (81), p.1288-1291
Main Authors: Li, Shu-Ying, Chen, Ting, Yue, Jie-Yu, Wang, Lin, Yan, Hui-Juan, Wang, Dong, Wan, Li-Jun
Format: Article
Language:English
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Amplification
Assemblies
Chirality
Correlation
Liquids
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description We systematically studied the operation of coadsorber-induced surface chirality in a series of enantiomeric surface supramolecular assemblies. The correlation of chiral amplification degree with the proportion of enantiomeric interaction in the total intermolecular interaction is deduced. Strong hydrogen bonding facilitates a more efficient amplification of chirality because of its critical role in chiral communication.
doi_str_mv 10.1039/c6cc05799c
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subjects Amplification
Assemblies
Chirality
Correlation
Liquids
title Manifesting the sergeants-and-soldiers principle in coadsorber induced homochiral polymorphic assemblies at the liquid/solid interface
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