Chiral signs of TPPS co-assemblies with chiral gelators: role of molecular and supramolecular chirality

A dianionic tetrakis(4-sulfonatophenyl)porphyrin (TPPS) self-assembled into J-aggregates when it co-assembled with a chiral cationic amphiphile via supramolecular gelation. The chiral signs of TPPS J aggregates followed the supramolecular chirality of amphiphilic assemblies rather than the molecular...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (84), p.12434-12437
Main Authors: Wang, Qiuling, Zhang, Li, Yang, Dong, Li, Tiesheng, Liu, Minghua
Format: Article
Language:English
Subjects:
Aggregates
Assemblies
Cationic
Chirality
Gelation
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Summary:A dianionic tetrakis(4-sulfonatophenyl)porphyrin (TPPS) self-assembled into J-aggregates when it co-assembled with a chiral cationic amphiphile via supramolecular gelation. The chiral signs of TPPS J aggregates followed the supramolecular chirality of amphiphilic assemblies rather than the molecular chirality of the amphiphile.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc05668g