Experimental research of hydroquinone (HQ)/hexamethylene tetramine (HMTA) gel for water plugging treatments in high‐temperature and high‐salinity reservoirs

• Published in: Journal of applied polymer science 2017-01, Vol.134 (1), p.np-n/a
• Main Authors: Fang, Jichao, Zhang, Xiao, He, Long, Zhao, Guang, Dai, Caili
• Format: Article
• Language: English
• Subjects: ageing; applications; characterization; Crosslinking; Enhanced oil recovery; Gelation; gels; Hexamethylene tetramine; Materials science; Microstructure; oil and gas; Plugging; Polymers; properties; Reservoirs; Strength
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.44359

ABSTRACT Polymer gel, as a water plugging treatment agent, has been successfully used in enhanced oil recovery (EOR) of mature oil fields. A new thermal‐resistance and salt‐tolerance polymer gel was developed based on HPAM and HQ/HMTA under the condition of high‐temperature (100.8 °C) and high‐salinity (up to 19.8 × 104 mg/L and Ca2+&Mg2+ 0.8 × 104 mg/L). The influence factors of gelling performance and coreflood performances were studied, the microstructure of the gel was observed with the environmental scanning electron microscopy, and gelation mechanism was proposed to illuminate the detailed gelation process. The gelation time decreases and the gel strength increases with the increase of polymer concentration, crosslinker concentration, or temperature. Although shearing had a negative effect on the viscosity of gelling solution, the gel strength, and the stability of gel have not been affected. The gelling solution has a good ability of injection and could selectively flow into high permeable zone. Additionally, the plugging rate increases and stays above 85% with the increase of the permeability or the gel strength. The microstructure of the gel confirms that the gel formed a three‐dimensional network structure. Based on the microstructure and the reaction process of the gel, a possible gelation mechanism is proposed. This study suggests that the gel system can be used in harsh reservoir conditions and the gelation time and gel strength can be controlled with adjusting the formation rate and the concentration of crosslinking agents. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 44359.