Facile Synthesis of Water-Soluble Cationic Tin(IV) Porphyrins and Water-Insoluble Tin(IV) Porphyrins in Water at Ambient Temperature

Novel environment-benign one-pot syntheses of water-soluble porphyrins, trans-dihydroxy-5,10,15,20-tetra(N-methyl-4′-pyridiniumyl)porphyrinate tin(IV) (Sn(IV)TMPyP(OH)2) and water-insoluble trans-dihydroxy-5,10,15,20-tetra(4-pyridyl)porphyrinate tin(IV) (Sn(IV)TPyP(OH)2), were found to proceed in wa...

Full description

Saved in:
Bibliographic Details
Published in:Bulletin of the Chemical Society of Japan 2016-08, Vol.89 (8), p.902-904
Main Authors: Thomas, Arun, Kuttassery, Fazalurahman, Remello, Seabatian Nybin, Mathew, Siby, Yamamoto, Daisuke, Onuki, Satomi, Nabetani, Yu, Tachibana, Hiroshi, Inoue, Haruo
Format: Article
Language:English
Subjects:
Ambient temperature
Cationic
Porphyrins
Solvents
Synthesis
Tin
Water chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Novel environment-benign one-pot syntheses of water-soluble porphyrins, trans-dihydroxy-5,10,15,20-tetra(N-methyl-4′-pyridiniumyl)porphyrinate tin(IV) (Sn(IV)TMPyP(OH)2) and water-insoluble trans-dihydroxy-5,10,15,20-tetra(4-pyridyl)porphyrinate tin(IV) (Sn(IV)TPyP(OH)2), were found to proceed in water as solvent at room temperature with high yield (90 and 93%).
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20160091