A 2D-g-C3N4 nanosheet as an eco-friendly adsorbent for various environmental pollutants in water

• Published in: Chemosphere (Oxford) 2017-03, Vol.171, p.192-201
• Main Authors: Cai, Xingguo, He, Junyong, Chen, Liang, Chen, Kai, Li, Yulian, Zhang, Kaisheng, Jin, Zhen, Liu, Jinyun, Wang, Chengming, Wang, Xuguang, Kong, Lingtao, Liu, Jinhuai
• Format: Article
• Language: English
• Subjects: Adsorption; Cadmium ion; g-C3N4 nanosheet; Methylene blue
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2016.12.073

A novel graphitic carbon nitride (g-C3N4) nanosheet adsorbent with a large surface area, remarkable hydrophilicity and high adsorption capacity, was presented for the removal of cadmium ions (Cd2+) and methylene blue (MB) from aqueous solution. Adsorption measurements were conducted systematically to study the influences of the contact time, initial concentrations of Cd2+ and MB, temperature, and pH value. The maximum adsorption capacities of g-C3N4 towards Cd2+ and MB were 94.4 and 42.1 mg g−1, respectively, at 318.5 K when the initial concentrations of Cd2+ and MB were 200 and 20 mg L−1, respectively. The adsorption kinetics fit a pseudo-second-order model. The high adsorption performance of the g-C3N4 adsorbent can be attributed to the multiple adsorption sites on g-C3N4, including the π-π conjugate interactions and electrostatic attractions with pollutants in water. In addition, it is significant to achieve high adsorption performance of g-C3N4 nanosheets by efficiently exposing the adsorption sites by adjusting the microstructure surface properties and dispersity in solution. [Display omitted] •An eco-friendly adsorbent 2D-g-C3N4 was prepared through simple pyrolysis.•2D-g-C3N4 can effectively remove Cd2+ and MB from water.•The adsorption mechanisms of Cd2+ and MB were proposed.