Synthesis and reactivity of N,N'-1,4-diazabutadiene derived borocations

A series of borocations have been synthesised from the addition of haloboranes to synthetically accessible N,N'-1,4-diazabutadiene precursors, which are derived from commercially available anilines. The synthesis and structural studies of the borocations are described.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (41), p.16177-16181
Main Authors: Lawson, James R, Wilkins, Lewis C, André, Manon, Richards, Emma C, Ali, Mohammed N, Platts, James A, Melen, Rebecca L
Format: Article
Language:English
Subjects:
Accessibility
Aniline
Precursors
Synthesis
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Description
Summary:A series of borocations have been synthesised from the addition of haloboranes to synthetically accessible N,N'-1,4-diazabutadiene precursors, which are derived from commercially available anilines. The synthesis and structural studies of the borocations are described.
ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt03360a