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Role of flexible bulky groups and weak interactions involving halogens in the vapoluminescence of a metal-free dye

A metal-free pyrazine dye exhibited vapoluminescence when exposed to benzene vapour. Single-crystal X-ray analysis revealed that its flexible bulky groups and weak interactions involving halogens play an essential role in the occurrence of the observed vapoluminescence.

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Bibliographic Details
Published in:RSC advances 2016-01, Vol.6 (78), p.74506-74509
Main Authors: Akune, Y., Hirosawa, R., Takahashi, H., Shiro, M., Matsumoto, S.
Format: Article
Language:English
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Description
Summary:A metal-free pyrazine dye exhibited vapoluminescence when exposed to benzene vapour. Single-crystal X-ray analysis revealed that its flexible bulky groups and weak interactions involving halogens play an essential role in the occurrence of the observed vapoluminescence.
ISSN:2046-2069
2046-2069
DOI:10.1039/C6RA15966D