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Time-Resolved InSitu X-ray Diffraction Reveals Metal-Dependent Metal-Organic Framework Formation

Versatility in metal substitution is one of the key aspects of metal-organic framework (MOF) chemistry, allowing properties to be tuned in a rational way. As a result, it important to understand why MOF syntheses involving different metals arrive at or fail to produce the same topological outcome. F...

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Published in:	Angewandte Chemie 2016-11, Vol.128 (45), p.14287-14290
Main Authors:	Wu, Yue, Henke, Sebastian, Kieslich, Gregor, Schwedler, Inke, Yang, Miaosen, Fraser, Duncan A X, O'Hare, Dermot
Format:	Article
Language:	eng ; ger
Subjects:	Breaking down Chemistry Diffraction Formations Kinetics Mathematical models Metal-organic frameworks Phases Reaction kinetics X-rays
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creator	Wu, Yue Henke, Sebastian Kieslich, Gregor Schwedler, Inke Yang, Miaosen Fraser, Duncan A X O'Hare, Dermot
description	Versatility in metal substitution is one of the key aspects of metal-organic framework (MOF) chemistry, allowing properties to be tuned in a rational way. As a result, it important to understand why MOF syntheses involving different metals arrive at or fail to produce the same topological outcome. Frequently, conditions are tuned by trial-and-error to make MOFs with different metal species. We ask: is it possible to adjust synthetic conditions in a systematic way in order to design routes to desired phases? We have used insitu X-ray powder diffraction to study the solvothermal formation of isostructural M2(bdc)2dabco (M=Zn, Co, Ni) pillared-paddlewheel MOFs in real time. The metal ion strongly influences both kinetics and intermediates observed, leading in some cases to multiphase reaction profiles of unprecedented complexity. The standard models used for MOF crystallization break down in these cases; we show that a simple kinetic model describes the data and provides important chemical insights on phase selection.
doi_str_mv	10.1002/ange.201608463
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subjects	Breaking down Chemistry Diffraction Formations Kinetics Mathematical models Metal-organic frameworks Phases Reaction kinetics X-rays
title	Time-Resolved InSitu X-ray Diffraction Reveals Metal-Dependent Metal-Organic Framework Formation
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