Affinity modulation of photoresponsive hosts for fullerenes: light-gated corannulene tweezers

Six azobenzene derivatives bearing polyaromatic fragments have been prepared and their reversible photoisomerization has been assessed. Corannulene-functionalized molecules have demonstrated excellent switchable hosting abilities towards fullerenes in which an interesting range of affinities has bee...

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Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (88), p.12964-12967
Main Authors: Barbero, Héctor, Ferrero, Sergio, Álvarez-Miguel, Lucía, Gómez-Iglesias, Patricia, Miguel, Daniel, Álvarez, Celedonio M
Format: Article
Language:English
Subjects:
Affinity
Bearing
Derivatives
Design analysis
Destruction
Formations
Fullerenes
Modulation
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cited_by cdi_FETCH-LOGICAL-c492t-6d2cf34bc46fb80df1f593882f373df83b89182eb95695291b159c0f68e702ce3
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description Six azobenzene derivatives bearing polyaromatic fragments have been prepared and their reversible photoisomerization has been assessed. Corannulene-functionalized molecules have demonstrated excellent switchable hosting abilities towards fullerenes in which an interesting range of affinities has been found. The success of this design relies upon the reversible formation and destruction of tweezer-like structures.
doi_str_mv 10.1039/c6cc06445k
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subjects Affinity
Bearing
Derivatives
Design analysis
Destruction
Formations
Fullerenes
Modulation
title Affinity modulation of photoresponsive hosts for fullerenes: light-gated corannulene tweezers
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