A Metamagnetic Two-Dimensional Molecular Material with Nickel(II) and Azide

Bridging azido ligands transmit both ferro‐ and antiferromagnetic interactions. The sheetlike structured complex [Ni(μ‐N3)2(N,N‐Et2‐N′‐Me‐en)]n (see picture) exhibits a range of magnetic behaviors at low temperature. Short‐range ferromagnetic and three‐dimensional antiferromagnetic ordering compete,...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2000-01, Vol.39 (1), p.191-193
Main Authors: Monfort, Montserrat, Resino, Immaculada, Ribas, Joan, Stoeckli-Evans, Helen
Format: Article
Language:English
Subjects:
azides
coordination chemistry
magnetic properties
N ligands
nickel
Online Access:Get full text
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Summary:Bridging azido ligands transmit both ferro‐ and antiferromagnetic interactions. The sheetlike structured complex [Ni(μ‐N3)2(N,N‐Et2‐N′‐Me‐en)]n (see picture) exhibits a range of magnetic behaviors at low temperature. Short‐range ferromagnetic and three‐dimensional antiferromagnetic ordering compete, giving metamagnetic behaviors. N,N‐Et2‐N′‐Me‐en=N,N‐diethyl‐N′‐methylethylenediamine.
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(20000103)39:1<191::AID-ANIE191>3.0.CO;2-F