Palladium-Catalyzed Additions of Silyl-Element Bonds to BicyclopropylideneA New Access to Bicyclopropyl and Functionally Substituted Cyclopropylidenepropane Derivatives

Palladium-catalyzed additions of disilanes, silylboranes, silylstannanes, and silyl cyanides across the double bond of bicyclopropylidene proceed with remarkable ease by two modes yielding either bicyclopropyl or cyclopropylidenepropane derivatives.

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Bibliographic Details
Published in:Organic letters 2000-11, Vol.2 (24), p.3877-3879
Main Authors: Pohlmann, Tim, de Meijere, Armin
Format: Article
Language:English
Online Access:Get full text
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Summary:Palladium-catalyzed additions of disilanes, silylboranes, silylstannanes, and silyl cyanides across the double bond of bicyclopropylidene proceed with remarkable ease by two modes yielding either bicyclopropyl or cyclopropylidenepropane derivatives.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol006618v