Molecular polarization and molecular chiralization: The first example of a chiralized xenon atom

In this article we focus on the interaction between a chiral molecule and a single achiral molecule or an ensemble of achiral molecules. The desymmetrization of the achiral molecules resulting from this interaction is described as “chiralization.” By analogy with electric polarization, we factorize...

Full description

Saved in:
Bibliographic Details
Published in:Chirality (New York, N.Y.) N.Y.), 2001, Vol.13 (1), p.2-6
Main Authors: Bartik, Kristin, Luhmer, Michel, Collet, André, Reisse, Jacques
Format: Article
Language:English
Subjects:
chirality
intermolecular interactions
multipolar polarizability
nuclear magnetic resonance
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-c3852-f9754750d48eb512aceb811792f824dbcaf64186aa9ad708eaf40d867c95338d3
container_end_page 6
container_issue 1
container_start_page 2
container_title Chirality (New York, N.Y.)
container_volume 13
creator Bartik, Kristin
Luhmer, Michel
Collet, André
Reisse, Jacques
description In this article we focus on the interaction between a chiral molecule and a single achiral molecule or an ensemble of achiral molecules. The desymmetrization of the achiral molecules resulting from this interaction is described as “chiralization.” By analogy with electric polarization, we factorize chiralization into three factors, i.e., orientation, atomic, and electronic terms. Chiralization depends on the dipolar polarizability of the chiralized molecule but also on polarizabilities of higher order. The experimental part of this work is devoted to the electronic chiralization of a xenon atom and its observation by 129Xe NMR spectroscopy. Chirality 13:2–6, 2001. © 2000 Wiley‐Liss, Inc.
doi_str_mv 10.1002/1520-636X(2001)13:1<2::AID-CHIR2>3.0.CO;2-U
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1859341735</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1859341735</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3852-f9754750d48eb512aceb811792f824dbcaf64186aa9ad708eaf40d867c95338d3</originalsourceid><addsrcrecordid>eNqNkE1v00AQQFcIREPhL6A9loPD7Jd3HVClyoEmakIQakRvw8ZeqwY7DruOSPn12DhKLxy47EozT2-kR4hgMGYA_C1THKJYxHcXHIC9YWLC3vPJ5Go-jdLZ_Au_FGMYp6t3PFo_IaMT_ZSMwCRJBCD5GXkRwncASGIhn5MzxphQEvSIfFs2lcv2lfV013Rv-du2ZbOldpvT-rTK7ktvq-NuQm_vHS1KH1rqDrbeVY42BbUnyuX04La9pG3ql-RZYavgXh3_c7L--OE2nUWL1fU8vVpEmTCKR0WildQKcmncRjFuM7cxjOmEF4bLfJPZIpbMxNYmNtdgnC0k5CbWWaKEMLk4JxeDd-ebn3sXWqzLkLmqslvX7AMyoxIhmRaqQ28GNPNNCN4VuPNlbf0DMsA-OfYRsY-IfXJkAhlyxC45_k2OAgHTVTdbd7bXx8P7Te3yR9excQcsB-BXWbmH_7z1r1PDoPNFg68MrTucfNb_wFgLrfDrp2ucmbtpvPi8xKn4AyQSqEI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1859341735</pqid></control><display><type>article</type><title>Molecular polarization and molecular chiralization: The first example of a chiralized xenon atom</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Bartik, Kristin ; Luhmer, Michel ; Collet, André ; Reisse, Jacques</creator><creatorcontrib>Bartik, Kristin ; Luhmer, Michel ; Collet, André ; Reisse, Jacques</creatorcontrib><description>In this article we focus on the interaction between a chiral molecule and a single achiral molecule or an ensemble of achiral molecules. The desymmetrization of the achiral molecules resulting from this interaction is described as “chiralization.” By analogy with electric polarization, we factorize chiralization into three factors, i.e., orientation, atomic, and electronic terms. Chiralization depends on the dipolar polarizability of the chiralized molecule but also on polarizabilities of higher order. The experimental part of this work is devoted to the electronic chiralization of a xenon atom and its observation by 129Xe NMR spectroscopy. Chirality 13:2–6, 2001. © 2000 Wiley‐Liss, Inc.</description><identifier>ISSN: 0899-0042</identifier><identifier>EISSN: 1520-636X</identifier><identifier>DOI: 10.1002/1520-636X(2001)13:1&lt;2::AID-CHIR2&gt;3.0.CO;2-U</identifier><identifier>PMID: 11135407</identifier><language>eng</language><publisher>New York: John Wiley &amp; Sons, Inc</publisher><subject>chirality ; intermolecular interactions ; multipolar polarizability ; nuclear magnetic resonance</subject><ispartof>Chirality (New York, N.Y.), 2001, Vol.13 (1), p.2-6</ispartof><rights>Copyright © 2001 Wiley‐Liss, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c3852-f9754750d48eb512aceb811792f824dbcaf64186aa9ad708eaf40d867c95338d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,4010,27904,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11135407$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bartik, Kristin</creatorcontrib><creatorcontrib>Luhmer, Michel</creatorcontrib><creatorcontrib>Collet, André</creatorcontrib><creatorcontrib>Reisse, Jacques</creatorcontrib><title>Molecular polarization and molecular chiralization: The first example of a chiralized xenon atom</title><title>Chirality (New York, N.Y.)</title><addtitle>Chirality</addtitle><description>In this article we focus on the interaction between a chiral molecule and a single achiral molecule or an ensemble of achiral molecules. The desymmetrization of the achiral molecules resulting from this interaction is described as “chiralization.” By analogy with electric polarization, we factorize chiralization into three factors, i.e., orientation, atomic, and electronic terms. Chiralization depends on the dipolar polarizability of the chiralized molecule but also on polarizabilities of higher order. The experimental part of this work is devoted to the electronic chiralization of a xenon atom and its observation by 129Xe NMR spectroscopy. Chirality 13:2–6, 2001. © 2000 Wiley‐Liss, Inc.</description><subject>chirality</subject><subject>intermolecular interactions</subject><subject>multipolar polarizability</subject><subject>nuclear magnetic resonance</subject><issn>0899-0042</issn><issn>1520-636X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNqNkE1v00AQQFcIREPhL6A9loPD7Jd3HVClyoEmakIQakRvw8ZeqwY7DruOSPn12DhKLxy47EozT2-kR4hgMGYA_C1THKJYxHcXHIC9YWLC3vPJ5Go-jdLZ_Au_FGMYp6t3PFo_IaMT_ZSMwCRJBCD5GXkRwncASGIhn5MzxphQEvSIfFs2lcv2lfV013Rv-du2ZbOldpvT-rTK7ktvq-NuQm_vHS1KH1rqDrbeVY42BbUnyuX04La9pG3ql-RZYavgXh3_c7L--OE2nUWL1fU8vVpEmTCKR0WildQKcmncRjFuM7cxjOmEF4bLfJPZIpbMxNYmNtdgnC0k5CbWWaKEMLk4JxeDd-ebn3sXWqzLkLmqslvX7AMyoxIhmRaqQ28GNPNNCN4VuPNlbf0DMsA-OfYRsY-IfXJkAhlyxC45_k2OAgHTVTdbd7bXx8P7Te3yR9excQcsB-BXWbmH_7z1r1PDoPNFg68MrTucfNb_wFgLrfDrp2ucmbtpvPi8xKn4AyQSqEI</recordid><startdate>2001</startdate><enddate>2001</enddate><creator>Bartik, Kristin</creator><creator>Luhmer, Michel</creator><creator>Collet, André</creator><creator>Reisse, Jacques</creator><general>John Wiley &amp; Sons, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>2001</creationdate><title>Molecular polarization and molecular chiralization: The first example of a chiralized xenon atom</title><author>Bartik, Kristin ; Luhmer, Michel ; Collet, André ; Reisse, Jacques</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3852-f9754750d48eb512aceb811792f824dbcaf64186aa9ad708eaf40d867c95338d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>chirality</topic><topic>intermolecular interactions</topic><topic>multipolar polarizability</topic><topic>nuclear magnetic resonance</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bartik, Kristin</creatorcontrib><creatorcontrib>Luhmer, Michel</creatorcontrib><creatorcontrib>Collet, André</creatorcontrib><creatorcontrib>Reisse, Jacques</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Chirality (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bartik, Kristin</au><au>Luhmer, Michel</au><au>Collet, André</au><au>Reisse, Jacques</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Molecular polarization and molecular chiralization: The first example of a chiralized xenon atom</atitle><jtitle>Chirality (New York, N.Y.)</jtitle><addtitle>Chirality</addtitle><date>2001</date><risdate>2001</risdate><volume>13</volume><issue>1</issue><spage>2</spage><epage>6</epage><pages>2-6</pages><issn>0899-0042</issn><eissn>1520-636X</eissn><abstract>In this article we focus on the interaction between a chiral molecule and a single achiral molecule or an ensemble of achiral molecules. The desymmetrization of the achiral molecules resulting from this interaction is described as “chiralization.” By analogy with electric polarization, we factorize chiralization into three factors, i.e., orientation, atomic, and electronic terms. Chiralization depends on the dipolar polarizability of the chiralized molecule but also on polarizabilities of higher order. The experimental part of this work is devoted to the electronic chiralization of a xenon atom and its observation by 129Xe NMR spectroscopy. Chirality 13:2–6, 2001. © 2000 Wiley‐Liss, Inc.</abstract><cop>New York</cop><pub>John Wiley &amp; Sons, Inc</pub><pmid>11135407</pmid><doi>10.1002/1520-636X(2001)13:1&lt;2::AID-CHIR2&gt;3.0.CO;2-U</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0899-0042
ispartof Chirality (New York, N.Y.), 2001, Vol.13 (1), p.2-6
issn 0899-0042
1520-636X
language eng
recordid cdi_proquest_miscellaneous_1859341735
source Wiley-Blackwell Read & Publish Collection
subjects chirality
intermolecular interactions
multipolar polarizability
nuclear magnetic resonance
title Molecular polarization and molecular chiralization: The first example of a chiralized xenon atom
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T23%3A50%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Molecular%20polarization%20and%20molecular%20chiralization:%20The%20first%20example%20of%20a%20chiralized%20xenon%20atom&rft.jtitle=Chirality%20(New%20York,%20N.Y.)&rft.au=Bartik,%20Kristin&rft.date=2001&rft.volume=13&rft.issue=1&rft.spage=2&rft.epage=6&rft.pages=2-6&rft.issn=0899-0042&rft.eissn=1520-636X&rft_id=info:doi/10.1002/1520-636X(2001)13:1%3C2::AID-CHIR2%3E3.0.CO;2-U&rft_dat=%3Cproquest_cross%3E1859341735%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c3852-f9754750d48eb512aceb811792f824dbcaf64186aa9ad708eaf40d867c95338d3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1859341735&rft_id=info:pmid/11135407&rfr_iscdi=true