Aromaticity as a Quantitative Concept. 6. Aromaticity Variation with Molecular Environment

The classical aromaticity of most heterocycles, and of some carbocycles such as azulene, increases with the polarity of the medium as shown by experimental and calculated bond lengths, aromaticity indices, and dipole moments.

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Bibliographic Details
Published in:Journal of organic chemistry 1996-03, Vol.61 (5), p.1619-1623
Main Authors: Katritzky, Alan R, Karelson, Mati, Wells, Adam P
Format: Article
Language:English
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Summary:The classical aromaticity of most heterocycles, and of some carbocycles such as azulene, increases with the polarity of the medium as shown by experimental and calculated bond lengths, aromaticity indices, and dipole moments.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo9516998