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Self-purification of marine environments for heavy metals: a study on removal of lead(II) and copper(II) by cuttlebone
The aim of this study was to determine adsorption properties of cuttlebone, cuttlefish bone as dead biomass, for lead(II) and copper(II) from aqueous solutions. Adsorption kinetic, isotherm and effect of pH (in the range of 2.0-7.0) were investigated in a single component batch system at room temper...
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Published in: | Water science and technology 2017-01, Vol.75 (2), p.474-481 |
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creator | Dobaradaran, Sina Nabipour, Iraj Keshtkar, Mozhgan Ghasemi, Fatemeh Faraji Nazarialamdarloo, Tayebeh Khalifeh, Farzaneh Poorhosein, Marjan Abtahi, Mehrnoosh Saeedi, Reza |
description | The aim of this study was to determine adsorption properties of cuttlebone, cuttlefish bone as dead biomass, for lead(II) and copper(II) from aqueous solutions. Adsorption kinetic, isotherm and effect of pH (in the range of 2.0-7.0) were investigated in a single component batch system at room temperature (25 ± 1 °C). The heavy metal adsorption by cuttlebone was relatively rapid and reached equilibrium in 120 min in all the cases. The pseudo-second order rate equation described the adsorption kinetic of both the ions. The adsorption capacities of Pb
and Cu
were constantly increased by pH and the optimum condition of pH was determined to be 7.0. The Freundlich model was better fitted than other models with the isotherm data, indicating sorption of the metal ions in a heterogeneous surface. According to the Langmuir model, the maximum adsorption capacities of cuttlebone for Pb
and Cu
were determined to be 45.9 and 39.9 mg/g, respectively. The results indicated cuttlebone as a promising adsorbent for Pb
and Cu
, which presents a high capacity of self-purification in marine environments and also can be used for removal of the metal ions from water and wastewater. |
doi_str_mv | 10.2166/wst.2016.533 |
format | article |
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and Cu
were constantly increased by pH and the optimum condition of pH was determined to be 7.0. The Freundlich model was better fitted than other models with the isotherm data, indicating sorption of the metal ions in a heterogeneous surface. According to the Langmuir model, the maximum adsorption capacities of cuttlebone for Pb
and Cu
were determined to be 45.9 and 39.9 mg/g, respectively. The results indicated cuttlebone as a promising adsorbent for Pb
and Cu
, which presents a high capacity of self-purification in marine environments and also can be used for removal of the metal ions from water and wastewater.</description><identifier>ISSN: 0273-1223</identifier><identifier>EISSN: 1996-9732</identifier><identifier>DOI: 10.2166/wst.2016.533</identifier><identifier>PMID: 28112674</identifier><language>eng</language><publisher>England: IWA Publishing</publisher><subject>Adsorbents ; Adsorption ; Aqueous solutions ; Beryllium ; Biomass ; Capacity ; Copper ; Copper compounds ; Equilibrium ; Experiments ; Fluorides ; Fourier transforms ; Hazardous materials ; Heavy metals ; Isotherms ; Lead ; Marine environment ; Marine molluscs ; Mathematical models ; Metal ions ; Metals ; Nanomaterials ; Nitrates ; pH effects ; Purification ; Removal ; Self-purification ; Solutions ; Sorption ; Surface chemistry ; Wastewater ; Wastewater treatment ; Water purification</subject><ispartof>Water science and technology, 2017-01, Vol.75 (2), p.474-481</ispartof><rights>Copyright IWA Publishing Jan 2017</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c357t-f5d992a4992659878a5eb8e351fb9fbde612a829b68ab196e9a49b34b6726be13</citedby><cites>FETCH-LOGICAL-c357t-f5d992a4992659878a5eb8e351fb9fbde612a829b68ab196e9a49b34b6726be13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28112674$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dobaradaran, Sina</creatorcontrib><creatorcontrib>Nabipour, Iraj</creatorcontrib><creatorcontrib>Keshtkar, Mozhgan</creatorcontrib><creatorcontrib>Ghasemi, Fatemeh Faraji</creatorcontrib><creatorcontrib>Nazarialamdarloo, Tayebeh</creatorcontrib><creatorcontrib>Khalifeh, Farzaneh</creatorcontrib><creatorcontrib>Poorhosein, Marjan</creatorcontrib><creatorcontrib>Abtahi, Mehrnoosh</creatorcontrib><creatorcontrib>Saeedi, Reza</creatorcontrib><title>Self-purification of marine environments for heavy metals: a study on removal of lead(II) and copper(II) by cuttlebone</title><title>Water science and technology</title><addtitle>Water Sci Technol</addtitle><description>The aim of this study was to determine adsorption properties of cuttlebone, cuttlefish bone as dead biomass, for lead(II) and copper(II) from aqueous solutions. Adsorption kinetic, isotherm and effect of pH (in the range of 2.0-7.0) were investigated in a single component batch system at room temperature (25 ± 1 °C). The heavy metal adsorption by cuttlebone was relatively rapid and reached equilibrium in 120 min in all the cases. The pseudo-second order rate equation described the adsorption kinetic of both the ions. The adsorption capacities of Pb
and Cu
were constantly increased by pH and the optimum condition of pH was determined to be 7.0. The Freundlich model was better fitted than other models with the isotherm data, indicating sorption of the metal ions in a heterogeneous surface. According to the Langmuir model, the maximum adsorption capacities of cuttlebone for Pb
and Cu
were determined to be 45.9 and 39.9 mg/g, respectively. The results indicated cuttlebone as a promising adsorbent for Pb
and Cu
, which presents a high capacity of self-purification in marine environments and also can be used for removal of the metal ions from water and wastewater.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Beryllium</subject><subject>Biomass</subject><subject>Capacity</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Equilibrium</subject><subject>Experiments</subject><subject>Fluorides</subject><subject>Fourier transforms</subject><subject>Hazardous materials</subject><subject>Heavy metals</subject><subject>Isotherms</subject><subject>Lead</subject><subject>Marine environment</subject><subject>Marine molluscs</subject><subject>Mathematical models</subject><subject>Metal ions</subject><subject>Metals</subject><subject>Nanomaterials</subject><subject>Nitrates</subject><subject>pH effects</subject><subject>Purification</subject><subject>Removal</subject><subject>Self-purification</subject><subject>Solutions</subject><subject>Sorption</subject><subject>Surface chemistry</subject><subject>Wastewater</subject><subject>Wastewater treatment</subject><subject>Water 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by cuttlebone</title><author>Dobaradaran, Sina ; Nabipour, Iraj ; Keshtkar, Mozhgan ; Ghasemi, Fatemeh Faraji ; Nazarialamdarloo, Tayebeh ; Khalifeh, Farzaneh ; Poorhosein, Marjan ; Abtahi, Mehrnoosh ; Saeedi, Reza</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c357t-f5d992a4992659878a5eb8e351fb9fbde612a829b68ab196e9a49b34b6726be13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Beryllium</topic><topic>Biomass</topic><topic>Capacity</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Equilibrium</topic><topic>Experiments</topic><topic>Fluorides</topic><topic>Fourier transforms</topic><topic>Hazardous materials</topic><topic>Heavy metals</topic><topic>Isotherms</topic><topic>Lead</topic><topic>Marine environment</topic><topic>Marine molluscs</topic><topic>Mathematical 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Reza</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Self-purification of marine environments for heavy metals: a study on removal of lead(II) and copper(II) by cuttlebone</atitle><jtitle>Water science and technology</jtitle><addtitle>Water Sci Technol</addtitle><date>2017-01-01</date><risdate>2017</risdate><volume>75</volume><issue>2</issue><spage>474</spage><epage>481</epage><pages>474-481</pages><issn>0273-1223</issn><eissn>1996-9732</eissn><abstract>The aim of this study was to determine adsorption properties of cuttlebone, cuttlefish bone as dead biomass, for lead(II) and copper(II) from aqueous solutions. Adsorption kinetic, isotherm and effect of pH (in the range of 2.0-7.0) were investigated in a single component batch system at room temperature (25 ± 1 °C). The heavy metal adsorption by cuttlebone was relatively rapid and reached equilibrium in 120 min in all the cases. The pseudo-second order rate equation described the adsorption kinetic of both the ions. The adsorption capacities of Pb
and Cu
were constantly increased by pH and the optimum condition of pH was determined to be 7.0. The Freundlich model was better fitted than other models with the isotherm data, indicating sorption of the metal ions in a heterogeneous surface. According to the Langmuir model, the maximum adsorption capacities of cuttlebone for Pb
and Cu
were determined to be 45.9 and 39.9 mg/g, respectively. The results indicated cuttlebone as a promising adsorbent for Pb
and Cu
, which presents a high capacity of self-purification in marine environments and also can be used for removal of the metal ions from water and wastewater.</abstract><cop>England</cop><pub>IWA Publishing</pub><pmid>28112674</pmid><doi>10.2166/wst.2016.533</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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issn | 0273-1223 1996-9732 |
language | eng |
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source | Alma/SFX Local Collection |
subjects | Adsorbents Adsorption Aqueous solutions Beryllium Biomass Capacity Copper Copper compounds Equilibrium Experiments Fluorides Fourier transforms Hazardous materials Heavy metals Isotherms Lead Marine environment Marine molluscs Mathematical models Metal ions Metals Nanomaterials Nitrates pH effects Purification Removal Self-purification Solutions Sorption Surface chemistry Wastewater Wastewater treatment Water purification |
title | Self-purification of marine environments for heavy metals: a study on removal of lead(II) and copper(II) by cuttlebone |
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