Continuous catalytic upgrading of ethanol to n-butanol over Cu-CeO2/AC catalysts

Cu-CeO2/AC catalysts exhibited extraordinary catalytic performance in the upgradation of ethanol to n-butanol. To the best of our knowledge, this is the first report that the highest n-butanol yields of 21.6% and nearly 20% could be achieved over heterogeneous catalysts under mild reaction condition...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (95), p.13749-13752
Main Authors: Jiang, Dahao, Wu, Xianyuan, Mao, Jun, Ni, Jun, Li, Xiaonian
Format: Article
Language:English
Subjects:
Catalysis
Catalysts
Catalytic activity
Ethanol
Ethyl alcohol
Reactors
Stability
Upgrading
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 13752
container_issue 95
container_start_page 13749
container_title Chemical communications (Cambridge, England)
container_volume 52
creator Jiang, Dahao
Wu, Xianyuan
Mao, Jun
Ni, Jun
Li, Xiaonian
description Cu-CeO2/AC catalysts exhibited extraordinary catalytic performance in the upgradation of ethanol to n-butanol. To the best of our knowledge, this is the first report that the highest n-butanol yields of 21.6% and nearly 20% could be achieved over heterogeneous catalysts under mild reaction conditions in batch and fixed-bed reactors, respectively. The high catalytic activity, selectivity and stability of these catalysts could be ascribed to the synergy of Cu, CeO2 and the activated carbon support.
doi_str_mv 10.1039/c6cc05860d
format article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_1864536094</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1835510318</sourcerecordid><originalsourceid>FETCH-LOGICAL-j287t-306ebd95cd09f26b24ee8570d24ee1ddb3146516d8412146cd3acd62473486c93</originalsourceid><addsrcrecordid>eNqNkM1KAzEUhYMoWKsbnyBLN7H5n2RZgn9QqAsFdyWTZOqUcVInieDbm2ofwLs534V7DpwLwDXBtwQzvXDSOSyUxP4EzAiTHAmu3k4PLDRqGBfn4CKlHa5DhJqBZxPH3I8llgSdzXb4zr2DZb-drO_HLYwdDPndjnGAOcIRtSX_LvErTNAUZMKaLpbm6E05XYKzzg4pXB11Dl7v717MI1qtH57McoV2VDUZMSxD67VwHuuOypbyEJRosD8A8b5lhEtBpFec0IrOM-u8pLx2UNJpNgc3f7n7KX6WkPLmo08uDIMdQy2zIUpywSTW_B-nTIj6vqo_ZhRfiA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1835510318</pqid></control><display><type>article</type><title>Continuous catalytic upgrading of ethanol to n-butanol over Cu-CeO2/AC catalysts</title><source>Royal Society of Chemistry</source><creator>Jiang, Dahao ; Wu, Xianyuan ; Mao, Jun ; Ni, Jun ; Li, Xiaonian</creator><creatorcontrib>Jiang, Dahao ; Wu, Xianyuan ; Mao, Jun ; Ni, Jun ; Li, Xiaonian</creatorcontrib><description>Cu-CeO2/AC catalysts exhibited extraordinary catalytic performance in the upgradation of ethanol to n-butanol. To the best of our knowledge, this is the first report that the highest n-butanol yields of 21.6% and nearly 20% could be achieved over heterogeneous catalysts under mild reaction conditions in batch and fixed-bed reactors, respectively. The high catalytic activity, selectivity and stability of these catalysts could be ascribed to the synergy of Cu, CeO2 and the activated carbon support.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c6cc05860d</identifier><language>eng</language><subject>Catalysis ; Catalysts ; Catalytic activity ; Ethanol ; Ethyl alcohol ; Reactors ; Stability ; Upgrading</subject><ispartof>Chemical communications (Cambridge, England), 2016-01, Vol.52 (95), p.13749-13752</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Jiang, Dahao</creatorcontrib><creatorcontrib>Wu, Xianyuan</creatorcontrib><creatorcontrib>Mao, Jun</creatorcontrib><creatorcontrib>Ni, Jun</creatorcontrib><creatorcontrib>Li, Xiaonian</creatorcontrib><title>Continuous catalytic upgrading of ethanol to n-butanol over Cu-CeO2/AC catalysts</title><title>Chemical communications (Cambridge, England)</title><description>Cu-CeO2/AC catalysts exhibited extraordinary catalytic performance in the upgradation of ethanol to n-butanol. To the best of our knowledge, this is the first report that the highest n-butanol yields of 21.6% and nearly 20% could be achieved over heterogeneous catalysts under mild reaction conditions in batch and fixed-bed reactors, respectively. The high catalytic activity, selectivity and stability of these catalysts could be ascribed to the synergy of Cu, CeO2 and the activated carbon support.</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Ethanol</subject><subject>Ethyl alcohol</subject><subject>Reactors</subject><subject>Stability</subject><subject>Upgrading</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqNkM1KAzEUhYMoWKsbnyBLN7H5n2RZgn9QqAsFdyWTZOqUcVInieDbm2ofwLs534V7DpwLwDXBtwQzvXDSOSyUxP4EzAiTHAmu3k4PLDRqGBfn4CKlHa5DhJqBZxPH3I8llgSdzXb4zr2DZb-drO_HLYwdDPndjnGAOcIRtSX_LvErTNAUZMKaLpbm6E05XYKzzg4pXB11Dl7v717MI1qtH57McoV2VDUZMSxD67VwHuuOypbyEJRosD8A8b5lhEtBpFec0IrOM-u8pLx2UNJpNgc3f7n7KX6WkPLmo08uDIMdQy2zIUpywSTW_B-nTIj6vqo_ZhRfiA</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Jiang, Dahao</creator><creator>Wu, Xianyuan</creator><creator>Mao, Jun</creator><creator>Ni, Jun</creator><creator>Li, Xiaonian</creator><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>Continuous catalytic upgrading of ethanol to n-butanol over Cu-CeO2/AC catalysts</title><author>Jiang, Dahao ; Wu, Xianyuan ; Mao, Jun ; Ni, Jun ; Li, Xiaonian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j287t-306ebd95cd09f26b24ee8570d24ee1ddb3146516d8412146cd3acd62473486c93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Ethanol</topic><topic>Ethyl alcohol</topic><topic>Reactors</topic><topic>Stability</topic><topic>Upgrading</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jiang, Dahao</creatorcontrib><creatorcontrib>Wu, Xianyuan</creatorcontrib><creatorcontrib>Mao, Jun</creatorcontrib><creatorcontrib>Ni, Jun</creatorcontrib><creatorcontrib>Li, Xiaonian</creatorcontrib><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jiang, Dahao</au><au>Wu, Xianyuan</au><au>Mao, Jun</au><au>Ni, Jun</au><au>Li, Xiaonian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Continuous catalytic upgrading of ethanol to n-butanol over Cu-CeO2/AC catalysts</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>52</volume><issue>95</issue><spage>13749</spage><epage>13752</epage><pages>13749-13752</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Cu-CeO2/AC catalysts exhibited extraordinary catalytic performance in the upgradation of ethanol to n-butanol. To the best of our knowledge, this is the first report that the highest n-butanol yields of 21.6% and nearly 20% could be achieved over heterogeneous catalysts under mild reaction conditions in batch and fixed-bed reactors, respectively. The high catalytic activity, selectivity and stability of these catalysts could be ascribed to the synergy of Cu, CeO2 and the activated carbon support.</abstract><doi>10.1039/c6cc05860d</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2016-01, Vol.52 (95), p.13749-13752
issn 1359-7345
1364-548X
language eng
recordid cdi_proquest_miscellaneous_1864536094
source Royal Society of Chemistry
subjects Catalysis
Catalysts
Catalytic activity
Ethanol
Ethyl alcohol
Reactors
Stability
Upgrading
title Continuous catalytic upgrading of ethanol to n-butanol over Cu-CeO2/AC catalysts
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T12%3A16%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Continuous%20catalytic%20upgrading%20of%20ethanol%20to%20n-butanol%20over%20Cu-CeO2/AC%20catalysts&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Jiang,%20Dahao&rft.date=2016-01-01&rft.volume=52&rft.issue=95&rft.spage=13749&rft.epage=13752&rft.pages=13749-13752&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c6cc05860d&rft_dat=%3Cproquest%3E1835510318%3C/proquest%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-j287t-306ebd95cd09f26b24ee8570d24ee1ddb3146516d8412146cd3acd62473486c93%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1835510318&rft_id=info:pmid/&rfr_iscdi=true