Preparation of polydopamine sulfamic acid-functionalized magnetic Fe3O4 nanoparticles with a core/shell nanostructure as heterogeneous and recyclable nanocatalysts for the acetylation of alcohols, phenols, amines and thiols under solvent-free conditions

• Published in: Green chemistry : an international journal and green chemistry resource : GC 2016-11, Vol.18 (23), p.6337-6348
• Main Authors: Veisi, Hojat, Taheri, Sepideh, Hemmati, Saba
• Format: Article
• Language: English
• Subjects: Alcohols; Catalysts; Fourier transforms; Nanoparticles; Nanostructure; Phenols; Transmission electron microscopy; X-rays
• ISSN: 1463-9262; 1463-9270
• DOI: 10.1039/c6gc01975g

A convenient method for the loading of sulfonic acid groups on the surface of polydopamine (PDA)-encapsulated Fe 3 O 4 nanoparticles is proposed to fabricate a core-shell Fe 3 O 4 @PDA-SO 3 H nanocatalyst. Such surface functionalization of magnetic particles is an elegant way to bridge the gap between heterogeneous and homogeneous catalysis. The as-prepared nanocatalyst was characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), wavelength-dispersive X-ray spectroscopy (WDX), thermogravimetric analysis (TGA), a vibrating sample magnetometer (VSM), X-ray photoelectron spectroscopy (XPS), and back titration. The Fe 3 O 4 @PDA-SO 3 H nanoparticles have been used as an efficient catalyst for the acetylation of a wide range of alcohols, phenols, amines and thiols with acetic anhydride in good to excellent yields under solvent-free conditions. Furthermore, the recovery and reuse of the catalyst was demonstrated 12 times without a detectible loss in activity. The loading of sulfonic acid groups on the surface of PDA-encapsulated Fe 3 O 4 nanoparticles is proposed to fabricate a core-shell Fe 3 O 4 @PDA-SO 3 H nanocatalyst.