R/X exchange reactions in cis-[M(R) 2 {P(X)(NMeCH 2 ) 2 } 2 ] (M = Pd, Pt), via a phosphenium intermediate

R/X exchange reactions in cis-[M(R) {P(X)(NMeCH ) } ] (M = Pd, Pt; R = aryl, alkyl; X = Cl, Br) were achieved for the first time to give cis-[M(X) {P(R)(NMeCH ) } ]. DFT calculations suggested that the exchange reaction proceeds via a phosphenium intermediate.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (48), p.19216-19220
Main Authors: Itazaki, Masumi, Tsuchida, Noriko, Shigesato, Yuka, Takano, Keiko, Nakazawa, Hiroshi
Format: Article
Language:English
Subjects:
Aromatic compounds
Exchange
Mathematical analysis
Palladium
Platinum
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Summary:R/X exchange reactions in cis-[M(R) {P(X)(NMeCH ) } ] (M = Pd, Pt; R = aryl, alkyl; X = Cl, Br) were achieved for the first time to give cis-[M(X) {P(R)(NMeCH ) } ]. DFT calculations suggested that the exchange reaction proceeds via a phosphenium intermediate.
ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt02314b