Alkenylation of Arenes and Heteroarenes with Alkynes

This review is focused on the analysis of current data on new methods of alkenylation of arenes and heteroarenes with alkynes by transition metal catalyzed reactions, Bronsted/Lewis acid promoted transformations, and others. The synthetic potential, scope, limitations, and mechanistic problems of th...

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Bibliographic Details
Published in:Chemical reviews 2016-05, Vol.116 (10), p.5894-5986
Main Authors: Boyarskiy, Vadim P, Ryabukhin, Dmitry S, Bokach, Nadezhda A, Vasilyev, Aleksander V
Format: Article
Language:English
Subjects:
Alkynes
Alkynes - chemistry
Aromatic compounds
Benzofurans - chemical synthesis
Benzofurans - chemistry
Catalysis
Chemical reactions
Derivatives
Heterocyclic Compounds - chemistry
Indoles - chemical synthesis
Indoles - chemistry
Lewis acid
Metals, Heavy - chemistry
Quinolines - chemical synthesis
Quinolines - chemistry
Rings (mathematics)
Styrene
Transformations
Transition Elements - chemistry
Transition metals
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Summary:This review is focused on the analysis of current data on new methods of alkenylation of arenes and heteroarenes with alkynes by transition metal catalyzed reactions, Bronsted/Lewis acid promoted transformations, and others. The synthetic potential, scope, limitations, and mechanistic problems of the alkenylation reactions are discussed. The insertion of an alkenyl group into aromatic and heteroaromatic rings by inter- or intramolecular ways provides a synthetic route to derivatives of styrene, stilbene, chalcone, cinnamic acid, various fused carbo- and heterocycles, etc.
ISSN:0009-2665
1520-6890
DOI:10.1021/acs.chemrev.5b00514