High-density insensitive energetic materials: 2,4,6-tris(2-fluoro-2,2-dinitroethoxy)-1,3,5-triazine

An efficient and reliable synthesis of 2,4,6-tris(2-fluoro-2,2-dinitroethoxy)-1,3,5-triazine ( 1 ) has been developed. The ether 1 was fully characterized by IR and multinuclear NMR spectroscopy, and X-ray crystal structure determinations. The compound exhibits good density, excellent thermal stabil...

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Bibliographic Details
Published in:RSC advances 2016-01, Vol.6 (16), p.14325-14329
Main Authors: Gidaspov, Alexander A, Bakharev, Vladimir V, Suponitsky, Kyrill Yu, Nikitin, Valery G, Sheremetev, Aleksei B
Format: Article
Language:English
Subjects:
Crystal structure
Density
Energetic materials
Ethers
Infrared spectroscopy
NMR spectroscopy
TNT
X-rays
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Summary:An efficient and reliable synthesis of 2,4,6-tris(2-fluoro-2,2-dinitroethoxy)-1,3,5-triazine ( 1 ) has been developed. The ether 1 was fully characterized by IR and multinuclear NMR spectroscopy, and X-ray crystal structure determinations. The compound exhibits good density, excellent thermal stability, and high performance, while impact sensitivities are comparable to TNT. A Na 3 PO 4 -promoted nucleophilic substitution of all chlorine atoms of cyanuric with fluorodinitroethanol was achieved with excellent yield. The product demonstrates promising potential for diverse applications like explosives or propellants.
ISSN:2046-2069
2046-2069
DOI:10.1039/c6ra24629j