Hydrocarbon liquid production viathe bioCRACK process and catalytic hydroprocessing of the product oil

Continuous hydroprocessing of liquid phase pyrolysis Bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfra...

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Bibliographic Details
Published in:Green chemistry : an international journal and green chemistry resource : GC 2015-04, Vol.17 (4), p.2487-2494
Main Authors: Schwaiger, N, Elliott, D C, Ritzberger, J, Wang, H, Pucher, P, Siebenhofer, M
Format: Article
Language:English
Subjects:
Carbon
Catalysis
Catalysts
Hydrocarbons
Hydrogen
Liquids
Pyrolysis
Quality assessment
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Summary:Continuous hydroprocessing of liquid phase pyrolysis Bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated Bio-oil. A sulfided base metal catalyst (CoMo on Al sub(2)O sub(3)) was evaluated. The bed of catalyst was operated at 400 degree C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (
ISSN:1463-9262
1463-9270
DOI:10.1039/c4gc02344g