Loading…

Novel deep eutectic solvent-functionalized carbon nanotubes adsorbent for mercury removal from water

[Display omitted] Due to the interestingly tolerated physicochemical properties of deep eutectic solvents (DESs), they are currently in the process of becoming widely used in many fields of science. Herein, we present a novel Hg2+ adsorbent that is based on carbon nanotubes (CNTs) functionalized by...

Full description

Saved in:

Bibliographic Details
Published in:	Journal of colloid and interface science 2017-07, Vol.497, p.413-421
Main Authors:	AlOmar, Mohamed Khalid, Alsaadi, Mohammed Abdulhakim, Jassam, Taha M., Akib, Shatirah, Ali Hashim, Mohd
Format:	Article
Language:	English
Subjects:	Adsorption Carbon nanotubes Deep eutectic solvents Functionalization Mercury
Citations:	Items that this one cites Items that cite this one
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

cited_by	cdi_FETCH-LOGICAL-c437t-629fe93aba714f15b74198294e0e5bc4dc9b840fea16fe883e940ff70e7cdc6e3
cites	cdi_FETCH-LOGICAL-c437t-629fe93aba714f15b74198294e0e5bc4dc9b840fea16fe883e940ff70e7cdc6e3
container_end_page	421
container_issue
container_start_page	413
container_title	Journal of colloid and interface science
container_volume	497
creator	AlOmar, Mohamed Khalid Alsaadi, Mohammed Abdulhakim Jassam, Taha M. Akib, Shatirah Ali Hashim, Mohd
description	[Display omitted] Due to the interestingly tolerated physicochemical properties of deep eutectic solvents (DESs), they are currently in the process of becoming widely used in many fields of science. Herein, we present a novel Hg2+ adsorbent that is based on carbon nanotubes (CNTs) functionalized by DESs. A DES formed from tetra-n-butyl ammonium bromide (TBAB) and glycerol (Gly) was used as a functionalization agent for CNTs. This novel adsorbent was characterized using Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, XRD, FESEM, EDX, BET surface area, and Zeta potential. Later, Hg2+ adsorption conditions were optimized using response surface methodology (RSM). A pseudo-second order model accurately described the adsorption of Hg2+. The Langmuir and Freundlich isotherm models described the absorption of Hg2+ on the novel adsorbent with acceptable accuracy. The maximum adsorption capacity was found to be 177.76mg/g.
doi_str_mv	10.1016/j.jcis.2017.03.014
format	article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1878818958</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0021979717302564</els_id><sourcerecordid>1878818958</sourcerecordid><originalsourceid>FETCH-LOGICAL-c437t-629fe93aba714f15b74198294e0e5bc4dc9b840fea16fe883e940ff70e7cdc6e3</originalsourceid><addsrcrecordid>eNp9kE1r3DAURUVoSSYffyCLoGU3dvRs2ZIgmxLSJhDSTbsWsvQEGmxrItlT0l9fDZNm2dXjwrkX3iHkGlgNDPrbbb21IdcNA1GztmbAT8gGmOoqAaz9RDaMNVApocQZOc95yxhA16lTctbIFjjwfkPcS9zjSB3ijuK6oF2CpTmOe5yXyq9zyXE2Y_iDjlqThjjT2cxxWQfM1Lgc01BI6mOiEya7pjeacIp7M1Kf4kR_mwXTJfnszZjx6v1ekF_fHn7eP1bPP74_3X99rixvxVL1jfKoWjMYAdxDNwgOSjaKI8NusNxZNUjOPBroPUrZoirJC4bCOttje0G-HHd3Kb6umBc9hWxxHM2Mcc0apJASpOpkQZsjalPMOaHXuxQmk940MH2wq7f6YFcf7GrW6mK3lG7e99dhQvdR-aezAHdHAMuX-4BJZxtwtuhCKmq1i-F_-38BGYWOBw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1878818958</pqid></control><display><type>article</type><title>Novel deep eutectic solvent-functionalized carbon nanotubes adsorbent for mercury removal from water</title><source>ScienceDirect Freedom Collection</source><creator>AlOmar, Mohamed Khalid ; Alsaadi, Mohammed Abdulhakim ; Jassam, Taha M. ; Akib, Shatirah ; Ali Hashim, Mohd</creator><creatorcontrib>AlOmar, Mohamed Khalid ; Alsaadi, Mohammed Abdulhakim ; Jassam, Taha M. ; Akib, Shatirah ; Ali Hashim, Mohd</creatorcontrib><description>[Display omitted] Due to the interestingly tolerated physicochemical properties of deep eutectic solvents (DESs), they are currently in the process of becoming widely used in many fields of science. Herein, we present a novel Hg2+ adsorbent that is based on carbon nanotubes (CNTs) functionalized by DESs. A DES formed from tetra-n-butyl ammonium bromide (TBAB) and glycerol (Gly) was used as a functionalization agent for CNTs. This novel adsorbent was characterized using Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, XRD, FESEM, EDX, BET surface area, and Zeta potential. Later, Hg2+ adsorption conditions were optimized using response surface methodology (RSM). A pseudo-second order model accurately described the adsorption of Hg2+. The Langmuir and Freundlich isotherm models described the absorption of Hg2+ on the novel adsorbent with acceptable accuracy. The maximum adsorption capacity was found to be 177.76mg/g.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2017.03.014</identifier><identifier>PMID: 28314146</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>Adsorption ; Carbon nanotubes ; Deep eutectic solvents ; Functionalization ; Mercury</subject><ispartof>Journal of colloid and interface science, 2017-07, Vol.497, p.413-421</ispartof><rights>2017 Elsevier Inc.</rights><rights>Copyright © 2017 Elsevier Inc. All rights reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c437t-629fe93aba714f15b74198294e0e5bc4dc9b840fea16fe883e940ff70e7cdc6e3</citedby><cites>FETCH-LOGICAL-c437t-629fe93aba714f15b74198294e0e5bc4dc9b840fea16fe883e940ff70e7cdc6e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28314146$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>AlOmar, Mohamed Khalid</creatorcontrib><creatorcontrib>Alsaadi, Mohammed Abdulhakim</creatorcontrib><creatorcontrib>Jassam, Taha M.</creatorcontrib><creatorcontrib>Akib, Shatirah</creatorcontrib><creatorcontrib>Ali Hashim, Mohd</creatorcontrib><title>Novel deep eutectic solvent-functionalized carbon nanotubes adsorbent for mercury removal from water</title><title>Journal of colloid and interface science</title><addtitle>J Colloid Interface Sci</addtitle><description>[Display omitted] Due to the interestingly tolerated physicochemical properties of deep eutectic solvents (DESs), they are currently in the process of becoming widely used in many fields of science. Herein, we present a novel Hg2+ adsorbent that is based on carbon nanotubes (CNTs) functionalized by DESs. A DES formed from tetra-n-butyl ammonium bromide (TBAB) and glycerol (Gly) was used as a functionalization agent for CNTs. This novel adsorbent was characterized using Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, XRD, FESEM, EDX, BET surface area, and Zeta potential. Later, Hg2+ adsorption conditions were optimized using response surface methodology (RSM). A pseudo-second order model accurately described the adsorption of Hg2+. The Langmuir and Freundlich isotherm models described the absorption of Hg2+ on the novel adsorbent with acceptable accuracy. The maximum adsorption capacity was found to be 177.76mg/g.</description><subject>Adsorption</subject><subject>Carbon nanotubes</subject><subject>Deep eutectic solvents</subject><subject>Functionalization</subject><subject>Mercury</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp9kE1r3DAURUVoSSYffyCLoGU3dvRs2ZIgmxLSJhDSTbsWsvQEGmxrItlT0l9fDZNm2dXjwrkX3iHkGlgNDPrbbb21IdcNA1GztmbAT8gGmOoqAaz9RDaMNVApocQZOc95yxhA16lTctbIFjjwfkPcS9zjSB3ijuK6oF2CpTmOe5yXyq9zyXE2Y_iDjlqThjjT2cxxWQfM1Lgc01BI6mOiEya7pjeacIp7M1Kf4kR_mwXTJfnszZjx6v1ekF_fHn7eP1bPP74_3X99rixvxVL1jfKoWjMYAdxDNwgOSjaKI8NusNxZNUjOPBroPUrZoirJC4bCOttje0G-HHd3Kb6umBc9hWxxHM2Mcc0apJASpOpkQZsjalPMOaHXuxQmk940MH2wq7f6YFcf7GrW6mK3lG7e99dhQvdR-aezAHdHAMuX-4BJZxtwtuhCKmq1i-F_-38BGYWOBw</recordid><startdate>20170701</startdate><enddate>20170701</enddate><creator>AlOmar, Mohamed Khalid</creator><creator>Alsaadi, Mohammed Abdulhakim</creator><creator>Jassam, Taha M.</creator><creator>Akib, Shatirah</creator><creator>Ali Hashim, Mohd</creator><general>Elsevier Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20170701</creationdate><title>Novel deep eutectic solvent-functionalized carbon nanotubes adsorbent for mercury removal from water</title><author>AlOmar, Mohamed Khalid ; Alsaadi, Mohammed Abdulhakim ; Jassam, Taha M. ; Akib, Shatirah ; Ali Hashim, Mohd</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c437t-629fe93aba714f15b74198294e0e5bc4dc9b840fea16fe883e940ff70e7cdc6e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Adsorption</topic><topic>Carbon nanotubes</topic><topic>Deep eutectic solvents</topic><topic>Functionalization</topic><topic>Mercury</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>AlOmar, Mohamed Khalid</creatorcontrib><creatorcontrib>Alsaadi, Mohammed Abdulhakim</creatorcontrib><creatorcontrib>Jassam, Taha M.</creatorcontrib><creatorcontrib>Akib, Shatirah</creatorcontrib><creatorcontrib>Ali Hashim, Mohd</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>AlOmar, Mohamed Khalid</au><au>Alsaadi, Mohammed Abdulhakim</au><au>Jassam, Taha M.</au><au>Akib, Shatirah</au><au>Ali Hashim, Mohd</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel deep eutectic solvent-functionalized carbon nanotubes adsorbent for mercury removal from water</atitle><jtitle>Journal of colloid and interface science</jtitle><addtitle>J Colloid Interface Sci</addtitle><date>2017-07-01</date><risdate>2017</risdate><volume>497</volume><spage>413</spage><epage>421</epage><pages>413-421</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><abstract>[Display omitted] Due to the interestingly tolerated physicochemical properties of deep eutectic solvents (DESs), they are currently in the process of becoming widely used in many fields of science. Herein, we present a novel Hg2+ adsorbent that is based on carbon nanotubes (CNTs) functionalized by DESs. A DES formed from tetra-n-butyl ammonium bromide (TBAB) and glycerol (Gly) was used as a functionalization agent for CNTs. This novel adsorbent was characterized using Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, XRD, FESEM, EDX, BET surface area, and Zeta potential. Later, Hg2+ adsorption conditions were optimized using response surface methodology (RSM). A pseudo-second order model accurately described the adsorption of Hg2+. The Langmuir and Freundlich isotherm models described the absorption of Hg2+ on the novel adsorbent with acceptable accuracy. The maximum adsorption capacity was found to be 177.76mg/g.</abstract><cop>United States</cop><pub>Elsevier Inc</pub><pmid>28314146</pmid><doi>10.1016/j.jcis.2017.03.014</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record>
fulltext	fulltext
identifier	ISSN: 0021-9797
ispartof	Journal of colloid and interface science, 2017-07, Vol.497, p.413-421
issn	0021-9797 1095-7103
language	eng
recordid	cdi_proquest_miscellaneous_1878818958
source	ScienceDirect Freedom Collection
subjects	Adsorption Carbon nanotubes Deep eutectic solvents Functionalization Mercury
title	Novel deep eutectic solvent-functionalized carbon nanotubes adsorbent for mercury removal from water
url	http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T19%3A32%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Novel%20deep%20eutectic%20solvent-functionalized%20carbon%20nanotubes%20adsorbent%20for%20mercury%20removal%20from%20water&rft.jtitle=Journal%20of%20colloid%20and%20interface%20science&rft.au=AlOmar,%20Mohamed%20Khalid&rft.date=2017-07-01&rft.volume=497&rft.spage=413&rft.epage=421&rft.pages=413-421&rft.issn=0021-9797&rft.eissn=1095-7103&rft_id=info:doi/10.1016/j.jcis.2017.03.014&rft_dat=%3Cproquest_cross%3E1878818958%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c437t-629fe93aba714f15b74198294e0e5bc4dc9b840fea16fe883e940ff70e7cdc6e3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1878818958&rft_id=info:pmid/28314146&rfr_iscdi=true