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Chemo-Catalyzed Pathways to Lactic Acid and Lactates

Lactic acid is an important building block for the production of biodegradable polymers (PLLA, PDLA, etc.) as well as starting material for the pharmaceutical industry. The current production of this chiral compound is dominated by fermentation processes. However many catalytic reactions that could...

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Published in:	Advanced synthesis & catalysis 2016-12, Vol.358 (24), p.3910-3931
Main Authors:	Shuklov, I. A., Dubrovina, N. V., Kühlein, K., Börner, A.
Format:	Article
Language:	English
Subjects:	Acids asymmetric catalysis Biodegradability Biodegradable materials carbonylation carboxylic acids Catalysis Chemical reactions Economics Efficiency Fermentation heterogeneous catalysis homogeneous catalysis hydrogenation Lactates Lactic acid Organic chemistry Polylactic acid Polymers
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description	Lactic acid is an important building block for the production of biodegradable polymers (PLLA, PDLA, etc.) as well as starting material for the pharmaceutical industry. The current production of this chiral compound is dominated by fermentation processes. However many catalytic reactions that could be used for manufacturing lactic acid were developed in the past three decades. High reaction rates and simple separation of products in comparison to fermentation characterize many of these processes. Excellent stereoselectivities up to 99% ee could be achieved. This review aims to give a critical overview of chemical processes applying catalysis as an alternative for the production of both enantiomerically pure and racemic lactic acid and lactates. The efficiency and economy of these processes are analyzed.
doi_str_mv	10.1002/adsc.201600768
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subjects	Acids asymmetric catalysis Biodegradability Biodegradable materials carbonylation carboxylic acids Catalysis Chemical reactions Economics Efficiency Fermentation heterogeneous catalysis homogeneous catalysis hydrogenation Lactates Lactic acid Organic chemistry Polylactic acid Polymers
title	Chemo-Catalyzed Pathways to Lactic Acid and Lactates
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