Synthesis and Characterization of S,N-Heteroacenes by Bischler-Napieralski Reaction

Bischler-Napieralski cyclization has been successfully employed to prepare planar S,N-heteroacenes（SNHs） with the analogue structures to 1,10-phenanthroline. The opto-/electrical properties and the packing modes of these S,Nheteroacenes were examined, which were dependent on the structure of the fus...

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Bibliographic Details
Published in:Chinese journal of polymer science 2016-11, Vol.34 (11), p.1319-1329
Main Authors: Guo, Hong-shuang, Liu, Mei-fang, Han, Yi, Han, Sheng, Chen, Yu-lan
Format: Article
Language:English
Subjects:
Characterization and Evaluation of Materials
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemoreceptors
Condensed Matter Physics
Copolymers
Electrical properties
Industrial Chemistry/Chemical Engineering
Molecular structure
Molecular weight
Polymer Sciences
Solubility
Solvents
Synthesis (chemistry)
传感器材料
光物理性质
合成
有机溶剂
环化反应
表征
邻菲罗啉
高分子量
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Summary:Bischler-Napieralski cyclization has been successfully employed to prepare planar S,N-heteroacenes（SNHs） with the analogue structures to 1,10-phenanthroline. The opto-/electrical properties and the packing modes of these S,Nheteroacenes were examined, which were dependent on the structure of the fused groups. SNH-based copolymers with high molecular weight and good solubility in common organic solvents or water have been synthesized by Suzuki-MiyauraSchlüter polycondensation. The photophysical property studies revealed that the copolymers may be a promising chemosensor material.
ISSN:0256-7679
1439-6203
DOI:10.1007/s10118-016-1846-9