Synthesis and Characterization of the First Nickel(II)-Centered Single-Side Tris-Functionalized Anderson-Type Polyoxomolybdate

The Ni‐centered Anderson‐type polyoxomolybdate [Ni(OH)3Mo6O18(OCH2)3CNH3]3– was prepared in a two‐step aqueous reaction by covalent postfunctionalization of [Ni(OH)6Mo6O18]4–, isolated as its sodium Tris–NH3 salt, and characterized by single‐crystal X‐ray diffraction, mass spectrometry, thermogravim...

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Bibliographic Details
Published in:European journal of inorganic chemistry 2016-12, Vol.2016 (36), p.5507-5511
Main Authors: Gumerova, Nadiia I., Roller, Alexander, Rompel, Annette
Format: Article
Language:English
Subjects:
Covalence
Crystal growth
Infrared spectroscopy
Ligands
Molybdenum
Nickel
Organic-inorganic hybrid composites
Parents
Polyoxometalates
Sodium
X-ray diffraction
X-rays
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Summary:The Ni‐centered Anderson‐type polyoxomolybdate [Ni(OH)3Mo6O18(OCH2)3CNH3]3– was prepared in a two‐step aqueous reaction by covalent postfunctionalization of [Ni(OH)6Mo6O18]4–, isolated as its sodium Tris–NH3 salt, and characterized by single‐crystal X‐ray diffraction, mass spectrometry, thermogravimetric analysis, and IR spectroscopy. The incorporation of a Tris–NH2 ligand into the framework of a heteropolymolybdate bearing a divalent heteroatom, which resulted in the single‐sided product, was shown for the first time. The first single‐side Tris‐functionalized Anderson‐type polyoxomolybdate containing a divalent heteroatom [NiII(OH)3Mo6O18(OCH2)3CNH3]3– is prepared via the presynthesized parent anion.
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.201601198