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Advancements in rationally designed PGM-free fuel cell catalysts derived from metal-organic frameworks
Over the past several years, metal-organic framework (MOF)-derived platinum group metal free (PGM-free) electrocatalysts have gained considerable attention due to their high efficiency and low cost as potential replacement for platinum in catalyzing oxygen reduction reaction (ORR). In this review, w...
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Published in: | Materials horizons 2017-01, Vol.4 (1), p.2-37 |
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Main Authors: | , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Over the past several years, metal-organic framework (MOF)-derived platinum group metal free (PGM-free) electrocatalysts have gained considerable attention due to their high efficiency and low cost as potential replacement for platinum in catalyzing oxygen reduction reaction (ORR). In this review, we summarize the recent advancements in design, synthesis and characterization of MOF-derived ORR catalysts and their performances in acidic and alkaline media. We also discuss the key challenges such as durability and activity enhancement critical in moving forward this emerging electrocatalyst science.
A comprehensive review revealed metal-organic frameworks as promising precursors for preparing highly active PGM-free electro-catalysts for oxygen reduction reaction. |
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ISSN: | 2051-6347 2051-6355 |
DOI: | 10.1039/c6mh00344c |