Three-dimensional reduced graphene oxide-grafted polyaniline aerogel as an active material for high performance supercapacitors

• Published in: Synthetic metals 2017-01, Vol.223, p.192-198
• Main Authors: Van Hoa, Nguyen, Quyen, Tran Thi Hoang, Van Hieu, Nguyen, Ngoc, Tran Quang, Thinh, Phan Vinh, Dat, Pham Anh, Nguyen, Hoang Thi Trang
• Format: Article
• Language: English
• Subjects: Aerogel; Aerogels; Capacitance; Chemical compounds; Chemical grafting; Coated electrodes; Electrochemical analysis; Electrodes; Glassy carbon; Grafting; Graphene; Oxides; Polyaniline; Polyanilines; Studies; Supercapacitor; Supercapacitors; Three dimensional composites
• ISSN: 0379-6779; 1879-3290
• DOI: 10.1016/j.synthmet.2016.11.021

[Display omitted] •3D RGO-g-PANI composite was efficiently prepared by a facile hydrothermal method.•The obtained specific capacitance was as high as 1600Fg−1 at 12Ag−1.•The cycling stability was 91.3% capacitance retention after 3000 cycles. Three-dimensional polyaniline grafted reduced graphene oxide (3D RGO-g-PANI) composite was prepared by an efficient two-step method. Firstly, graphene oxide sheets were grafted with PANI chains, forming graphene oxide grafted PANI composites. Secondly, RGO-g-PANI aerogels were obtained from GO-g-PANI composites by hydrothermal and drying processes. The 3D RGO-g-PANI aerogel composite was used as active materials to coat the glassy carbon electrodes for checking the electrochemical properties for supercapacitor application. The obtained specific capacitance was 1600Fg−1 at a very high current density of 12Ag−1 and an excellent cycle stability (91.3% capacitance retention after 3000 cycles), suggesting its potential application for a high performance supercapacitors.