Microstructure, surface characterization and long-term stability of new quaternary Ti-Zr-Ta-Ag alloy for implant use

• Published in: Materials Science & Engineering C 2017-02, Vol.71, p.322-334
• Main Authors: Vasilescu, C., Osiceanu, P., Moreno, J.M. Calderon, Drob, S.I., Preda, S., Popa, M., Dan, I., Marcu, M., Prodana, M., Popovici, I.A., Ionita, D., Vasilescu, E.
• Format: Article
• Language: English
• Subjects: Alloys; Alloys - chemistry; Anti-Bacterial Agents - chemistry; Antibacterial activity; Biocompatibility; Corrosion; Corrosion rate; Corrosion resistance; Corrosion resistant alloys; EIS; Electrochemistry; High resistance; Hydroxyapatite; Implants, Experimental; Materials science; Mechanical properties; Microstructure; Microstructure (XRD, SEM, EDS); Parameters; pH effects; Protective coatings; Silver - chemistry; Silver base alloys; Stability; Surface properties; Surface stability; Surgical implants; Tantalum base alloys; Thickening; Thickness; Ti-20Zr-5Ta-2Ag alloy; Time Factors; Titanium - chemistry; Titanium base alloys; X ray photoelectron spectroscopy; XPS; Zirconium - chemistry; Zirconium base alloys
• ISSN: 0928-4931; 1873-0191
• DOI: 10.1016/j.msec.2016.10.004

The novel Ti-20Zr-5Ta-2Ag alloy was characterised concerning its microstructure, morphology, mechanical properties, its passive film composition and thickness, its long-term electrochemical stability, corrosion resistance, ion release rate in Ringer solution of acid, neutral and alkaline pH values and antibacterial activity. The new alloy has a crystalline α microstructure (by XRD). Long-term XPS and SEM analyses show the thickening of the passive film and the deposition of hydroxyapatite in neutral and alkaline Ringer solution. The values of the electrochemical parameters confirm the over time stability of the new alloy passive film. All corrosion parameters have very favourable values in time which attest a high resistance to corrosion. Impedance spectra evinced a bi-layered passive film formed by the barrier, insulating layer and the porous layer. The monitoring of the open circuit potentials indicated the stability of the protective layers and their thickening in time. The new alloy releases (by ICP-MS measurements) very low quantities of Ti, Zr, Ag ions and no Ta ions. The new alloy exhibits a low antibacterial activity. •New Ti-20Zr-5Ta-2Ag alloy shows a pseudo-lamellar structure of α phase (optical, SEM and XRD)•Surface morphology (by SEM) reveals newly formed layers after 1500 h in physiological solution•XPS analysis determined over time thickening of passive film and of deposited hydroxyapatite•Electrochemical and corrosion parameters present more favourable values in time•Ion release rate of Ag+ ions (by ICP-MS) is under the toxicity limits for cells