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Au nanoparticles decorated polypyrrole/reduced graphene oxide hybrid sheets for ultrasensitive dopamine detection

•A new strategy to improve the sensitivity of PPy/GS composite sensors is proposed.•Au@PPy/GS composite was facilely synthesized by the novel initiation of HAuCl4.•The prepared composite is dramatically obtained a crumpled and wrinkled surface.•The flower-like Au nanoparticles are decorated on the P...

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Bibliographic Details
Published in:Sensors and actuators. B, Chemical Chemical, 2014-03, Vol.193, p.759-763
Main Authors: Qian, Tao, Yu, Chenfei, Zhou, Xi, Wu, Shishan, Shen, Jian
Format: Article
Language:English
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Summary:•A new strategy to improve the sensitivity of PPy/GS composite sensors is proposed.•Au@PPy/GS composite was facilely synthesized by the novel initiation of HAuCl4.•The prepared composite is dramatically obtained a crumpled and wrinkled surface.•The flower-like Au nanoparticles are decorated on the PPy/GS hybrid sheets.•Au@PPy/GS sensor offers an ultrasensitive detection for DA in biological systems. Au nanoparticles decorated polypyrrole/reduced graphene oxide hybrid sheets were facilely fabricated through a facile process. The prepared composite is dramatically obtained a crumpled and wrinkled surface, and uniform flower-like Au nanoparticles, which significantly improve the electrochemical properties in nano-molar level detection of dopamine. The novel sensor exhibits a remarkable sensitivity of 16.40μA/μM with a linear range of 0.1–5000nM and limit of detection as low as18.29pM.
ISSN:0925-4005
1873-3077
DOI:10.1016/j.snb.2013.12.055