Palladium/zinc co-catalyzed asymmetric transfer hydrogenation of oxabenzonorbornadienes with alcohols as hydrogen sources

Asymmetric transfer hydrogenation of oxabenzonorbornadienes was realized by using alcohols as hydrogen sources under a co-catalytic system of palladium and zinc. Both primary and secondary alcohols could serve as reductants and afforded enantiomerically enriched 1,2-dihydronaphth-1-ol products with...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2017-03, Vol.15 (11), p.2359-2362
Main Authors: Ma, Fujie, Chen, Jingchao, Yang, Fan, Shinde, Madhuri Vikas, Zhou, Yongyun, Fan, Baomin
Format: Article
Language:English
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Summary:Asymmetric transfer hydrogenation of oxabenzonorbornadienes was realized by using alcohols as hydrogen sources under a co-catalytic system of palladium and zinc. Both primary and secondary alcohols could serve as reductants and afforded enantiomerically enriched 1,2-dihydronaphth-1-ol products with high optical purities.
ISSN:1477-0520
1477-0539
DOI:10.1039/c7ob00175d