Transition‐Metal‐Catalyzed Electrophilic Amination: Application of O‐Benzoylhydroxylamines in the Construction of the C−N Bond

Transition‐metal‐catalyzed electrophilic amination has been developed into a powerful tool for C−N bond construction. So far, O‐benzoylhydroxylamines are the most widely used electrophilic aminating reagents. Herein, we summarize the recent advances of O‐benzoylhydroxylamines involved in electrophil...

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Bibliographic Details
Published in:Chemistry : a European journal 2017-02, Vol.23 (11), p.2481-2511
Main Authors: Dong, Xu, Liu, Qing, Dong, Yunhui, Liu, Hui
Format: Article
Language:English
Subjects:
Bonding
Chemical bonds
Chemistry
Construction equipment
cross-coupling
electrophilic amination
O-benzoylhydroxylamines
Reagents
tertiary amines
Transition metals
transition-metal catalysis
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Summary:Transition‐metal‐catalyzed electrophilic amination has been developed into a powerful tool for C−N bond construction. So far, O‐benzoylhydroxylamines are the most widely used electrophilic aminating reagents. Herein, we summarize the recent advances of O‐benzoylhydroxylamines involved in electrophilic amination catalyzed by transition metals. Several pioneering studies and some of the relevant mechanisms are discussed in this review. Powerful aminating reagent: Application of O‐benzoylhydroxylamines in transition‐metal‐catalyzed electrophilic amination has received rapid development in the construction of the C−N bond (see scheme). In this review, we summarize the recent advances in this field since 2004. Several pioneering works and some of the relevant mechanisms are discussed.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201601607