Ruthenium-catalyzed regioselective allylic amination of 2,3,3-trifluoroallylic carbonates

We demonstrated the ruthenium-catalyzed allylic amination of 2,3,3-trifluoroallylic carbonates with several types of amines. The reactions proceeded with several types of amines, and succeeded in obtaining polyfluorinated terminal alkenes possessing branched allylic amines as a single regioisomer.

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2017, Vol.15 (14), p.2938-2946
Main Authors: Isobe, Shin-Ichi, Terasaki, Shou, Hanakawa, Taisyun, Mizuno, Shota, Kawatsura, Motoi
Format: Article
Language:English
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Summary:We demonstrated the ruthenium-catalyzed allylic amination of 2,3,3-trifluoroallylic carbonates with several types of amines. The reactions proceeded with several types of amines, and succeeded in obtaining polyfluorinated terminal alkenes possessing branched allylic amines as a single regioisomer.
ISSN:1477-0520
1477-0539
DOI:10.1039/c7ob00514h