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Transformation of the ionic liquid [EMIM][B(CN) 4 ] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions

The lanthanum tetracyanoborate coordination polymers [EMIM] [LaNO {B(CN) } (H O) ] (EMIM = 1-ethyl-3-methylimidazolium) and [La(NO ) [B(CN) ](H O) ] mark first examples of Ln-tetracyanoborates that have been obtained in ionothermal syntheses without further solvents to influence e.g. viscosity. Ther...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017-05, Vol.53 (37), p.5193-5195
Main Authors: Zottnick, Sven H, Finze, Maik, Müller-Buschbaum, Klaus
Format: Article
Language:English
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Summary:The lanthanum tetracyanoborate coordination polymers [EMIM] [LaNO {B(CN) } (H O) ] (EMIM = 1-ethyl-3-methylimidazolium) and [La(NO ) [B(CN) ](H O) ] mark first examples of Ln-tetracyanoborates that have been obtained in ionothermal syntheses without further solvents to influence e.g. viscosity. Thereby, the ionic liquid [EMIM][B(CN) ] is fully incorporated into product formation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc01378g