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Transformation of the ionic liquid [EMIM][B(CN) 4 ] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions
The lanthanum tetracyanoborate coordination polymers [EMIM] [LaNO {B(CN) } (H O) ] (EMIM = 1-ethyl-3-methylimidazolium) and [La(NO ) [B(CN) ](H O) ] mark first examples of Ln-tetracyanoborates that have been obtained in ionothermal syntheses without further solvents to influence e.g. viscosity. Ther...
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Published in: | Chemical communications (Cambridge, England) England), 2017-05, Vol.53 (37), p.5193-5195 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The lanthanum tetracyanoborate coordination polymers [EMIM] [LaNO
{B(CN)
}
(H
O)
] (EMIM = 1-ethyl-3-methylimidazolium) and [La(NO
)
[B(CN)
](H
O)
] mark first examples of Ln-tetracyanoborates that have been obtained in ionothermal syntheses without further solvents to influence e.g. viscosity. Thereby, the ionic liquid [EMIM][B(CN)
] is fully incorporated into product formation. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c7cc01378g |