An insight into the mechanism of the aerobic oxidation of aldehydes catalyzed by N-heterocyclic carbenes

N-Heterocyclic carbene catalysis for the aerobic oxidation and esterification of aromatic aldehydes was monitored by ESI-MS (MS/MS) and the key intermediates were intercepted and characterized using the charge-tag strategy.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (16), p.2008-2011
Main Authors: Bortolini, O, Chiappe, C, Fogagnolo, M, Giovannini, P P, Massi, A, Pomelli, C S, Ragno, D
Format: Article
Language:English
Subjects:
Aldehydes
Aldehydes - chemistry
Carbenes
Carboxylic Acids - chemical synthesis
Carboxylic Acids - chemistry
Catalysis
Esterification
Heterocyclic Compounds - chemistry
Methane - analogs & derivatives
Methane - chemistry
Molecular Structure
Monitoring
Oxidation
Oxidation-Reduction
Strategy
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Description
Summary:N-Heterocyclic carbene catalysis for the aerobic oxidation and esterification of aromatic aldehydes was monitored by ESI-MS (MS/MS) and the key intermediates were intercepted and characterized using the charge-tag strategy.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48929a