Catalytic enantioselective bromoamination of allylic alcohols

An enantioselective bromoamination of allylic alcohols has been developed for the first time using a newly designed cinchona-derived thiourea as the catalyst and N,N-dibromo-4-nitrobenzenesulfonamide as a bromine and amine source.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (89), p.13841-13844
Main Authors: Qi, Juan, Fan, Guo-Tao, Chen, Jie, Sun, Ming-Hui, Dong, Yu-Ting, Zhou, Ling
Format: Article
Language:English
Subjects:
Alcohols
Amines
Bromine
Catalysis
Catalysts
Thioureas
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Description
Summary:An enantioselective bromoamination of allylic alcohols has been developed for the first time using a newly designed cinchona-derived thiourea as the catalyst and N,N-dibromo-4-nitrobenzenesulfonamide as a bromine and amine source.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc05772d