A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition

In addition to the generally observed LIESST phenomenon, polymorph D of trans-[Fe(II)(abpt)(2)(NCS)(2)] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-06, Vol.48 (46), p.5715-5717
Main Authors: Sheu, Chou-Fu, Shih, Che-Hsiu, Sugimoto, Kunihisa, Cheng, Bing-Ming, Takata, Masaki, Wang, Yu
Format: Article
Language:English
Subjects:
Crossovers
Isomerization
Linkages
Metastable state
Spin transition
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Description
Summary:In addition to the generally observed LIESST phenomenon, polymorph D of trans-[Fe(II)(abpt)(2)(NCS)(2)] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc31326j