A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition

In addition to the generally observed LIESST phenomenon, polymorph D of trans-[Fe(II)(abpt)(2)(NCS)(2)] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K.

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Published in:Chemical communications (Cambridge, England) England), 2012-06, Vol.48 (46), p.5715-5717
Main Authors: Sheu, Chou-Fu, Shih, Che-Hsiu, Sugimoto, Kunihisa, Cheng, Bing-Ming, Takata, Masaki, Wang, Yu
Format: Article
Language:English
Subjects:
Crossovers
Isomerization
Linkages
Metastable state
Spin transition
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cited_by cdi_FETCH-LOGICAL-c320t-474f48107c6a5a76a339499f9acdcca2a023eabc74a0e0380873797c57b0003f3
cites cdi_FETCH-LOGICAL-c320t-474f48107c6a5a76a339499f9acdcca2a023eabc74a0e0380873797c57b0003f3
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container_issue 46
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container_title Chemical communications (Cambridge, England)
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creator Sheu, Chou-Fu
Shih, Che-Hsiu
Sugimoto, Kunihisa
Cheng, Bing-Ming
Takata, Masaki
Wang, Yu
description In addition to the generally observed LIESST phenomenon, polymorph D of trans-[Fe(II)(abpt)(2)(NCS)(2)] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K.
doi_str_mv 10.1039/c2cc31326j
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source Royal Society of Chemistry
subjects Crossovers
Isomerization
Linkages
Metastable state
Spin transition
title A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition
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